1) How many moles of gas occupy 58 L at a pressure of 1.55 atmospheres and a temperature of 222
K?

Answers

Answer 1

To find the moles of the gas , we can use the ideal gas law. Which states -

[tex] \:\:\:\:\:\:\:\:\:\star\longrightarrow \sf \underline{PV=nRT} \\[/tex]

Where:-

P is the pressure measured in atmospheres V is the volume measured in litersn is the number of moles.R is the ideal gas constant (0.0821 L atm mol⁻¹ K⁻¹).T is the temperature measured in kelvin.

As per question, we are given that-

P=1.55 atmV= 58 LT = 222 KR = 0.08206 L atm mol⁻¹ K⁻¹

Now that we have all the required values, so we can put them all in the Ideal gas law formula and solve for moles -

[tex] \:\:\:\:\:\:\:\:\:\star\longrightarrow \sf \underline{PV=nRT} \\[/tex]

[tex] \:\:\:\:\:\:\:\:\:\longrightarrow \sf 1.55 \times 58 = n \times 0.0821 \times 222\\[/tex]

[tex] \:\:\:\:\:\:\:\:\:\longrightarrow \sf 89.9 = n \times 18.2262\\[/tex]

[tex] \:\:\:\:\:\:\:\:\:\longrightarrow \sf n \times 18.2262 =89.9\\[/tex]

[tex] \:\:\:\:\:\:\:\:\:\:\:\:\longrightarrow \sf n = \dfrac{89.9}{18.2262}\\[/tex]

[tex] \:\:\:\:\:\:\:\:\:\:\:\:\longrightarrow \sf n =4.9324......\\[/tex]

[tex]\:\:\:\:\:\: \:\:\:\:\:\:\longrightarrow \sf \underline{n =4.93 \:moles }\\[/tex]

Therefore, 4.93 moles of gas will be occupied 58 L at a pressure of 1.55 atmospheres and a temperature of 222 k


Related Questions

a common temperature-sensing component that reacts to temperature change by changing shape to actuate a reed switch or mercury switch is a

Answers

thermostat. A thermostat is a device that automatically maintains a desired temperature within a system by controlling the heating or cooling equipment.

It typically consists of a temperature sensor that measures the temperature of the system, a control unit that compares the measured temperature with the desired temperature and determines whether heating or cooling is needed, and a switching mechanism that activates the heating or cooling equipment. The most common types of thermostats are mechanical, digital, and programmable. Mechanical thermostats use a bimetallic strip that expands or contracts with temperature changes to activate a switch, while digital and programmable thermostats use electronic sensors and microprocessors to control the temperature more accurately and allow for customized scheduling.

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discuss the relative importance of various mechanical and chemical factors in producing respiratory variations.

Answers

Respiratory variations can be influenced by a variety of mechanical and chemical factors. Mechanical factors include changes in lung volume and airway resistance, while chemical factors include changes in blood oxygen and carbon dioxide levels. The relative importance of these factors in producing respiratory variations can depend on a variety of factors, including the individual's health status, level of physical activity, and environmental conditions.

In healthy individuals, mechanical factors such as changes in lung volume and airway resistance play a primary role in producing respiratory variations. For example, during exercise or physical activity, increased demand for oxygen can lead to deeper and more frequent breaths as the lungs work harder to supply oxygen to the body. Conversely, during periods of relaxation or sleep, respiratory rate and volume decrease as the body's oxygen demand decreases.

Chemical factors can also play a significant role in producing respiratory variations. Changes in blood oxygen and carbon dioxide levels can stimulate the respiratory center in the brain, leading to changes in breathing rate and depth. For example, when blood carbon dioxide levels increase, the respiratory center is stimulated, causing an increase in breathing rate and depth to remove excess carbon dioxide from the body.

Overall, while both mechanical and chemical factors can contribute to respiratory variations, the relative importance of these factors can vary depending on the individual and their circumstances. Understanding the interplay between these factors can be important for managing respiratory conditions and promoting respiratory health.

The relative importance of each factor depends on the specific situation and individual conditions. Generally, chemical factors are more important in regulating breathing and maintaining homeostasis, while mechanical factors are essential for the proper functioning of the respiratory system.

The relative importance of mechanical and chemical factors in producing respiratory variations can be discussed by examining their roles in regulating breathing and maintaining homeostasis.

1. Mechanical Factors:

- Lung compliance: It refers to the ease with which lungs can be expanded. Higher compliance means the lungs can expand more easily, resulting in a lower breathing effort. Changes in lung compliance can lead to variations in respiratory patterns.
- Airway resistance: The resistance encountered by the airflow in the respiratory tract determines the ease of breathing. Increased airway resistance can lead to respiratory variations, such as difficulty in breathing.
- Chest wall and diaphragm movement: The coordinated contraction and relaxation of the diaphragm and chest wall muscles play a crucial role in breathing. Any abnormalities in these movements can lead to respiratory variations.

2. Chemical Factors:

- Oxygen levels: Low oxygen levels in the blood (hypoxia) can lead to increased breathing rate and depth to maintain proper oxygen supply to the tissues.
- Carbon dioxide levels: High carbon dioxide levels in the blood (hypercapnia) stimulate chemoreceptors, which in turn increase the breathing rate and depth to eliminate excess [tex]CO_2[/tex] from the body.
- Hydrogen ion concentration (pH): Chemoreceptors also respond to changes in blood pH. Acidosis (low pH) due to high hydrogen ion concentration can increase the breathing rate and depth to eliminate [tex]CO_2[/tex] and restore the pH balance.

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a trial run takes 42 seconds for the blue color to appear. the rate of reaction for this trial will be

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The rate of reaction is 0.001 M/s. The answer is option e.

The rate of a reaction refers to the change in concentration of reactants or products per unit time. It is typically expressed in units of M/s, where M refers to the molarity of the solution (moles of solute per liter of solution). The rate constant (k) for a first-order reaction can be calculated using the half-life equation t1/2 = ln(2)/k.

In this case, t1/2 = 100 seconds, so k = ln(2)/t1/2 = 0.0069 s^-1.

The rate of reaction can be calculated using the first-order rate law, rate = k[A], where [A] is the concentration of the reactant.

Substituting the value, we get

rate = 0.0069 x 0.01 = 0.000069 M/s,

which is approximately equal to 0.001 M/s. Therefore, the answer is option e.

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--The complete question is. What is the rate of the reaction in M/s for Experiment 3, given that the concentration of one of the reactants or products is 0.01 M and the reaction follows first-order kinetics? The time it takes for the reaction to reach half completion is 100 seconds. The options provided are 0.22, 0.11, 0.005, 0.01, and 0.001 M/s.--

) H₂C=CH₂ H₂ Ni
What is the reaction scheme​

Answers

Based on the presence of hydrogen gas (H₂) and nickel (Ni), it is possible that this is a hydrogenation reaction in which the double bond in H₂C=CH₂ is converted to a single bond.

What is a hydrogenation reaction?

Hydrogenation is a chemical reaction in which hydrogen gas (H₂) is added to a molecule, typically an unsaturated organic compound, to form a saturated molecule. The reaction is usually catalyzed by a metal catalyst, such as nickel or palladium, and typically occurs at high pressure and temperature.

The addition of hydrogen atoms to an unsaturated molecule, such as an alkene or alkyne, can convert it to a saturated molecule, such as an alkane. This process is widely used in the food industry to convert unsaturated fats and oils into saturated fats and oils, which have a longer shelf life and are more stable at high temperatures.

The balanced equation for this reaction is:

H₂C=CH₂ + H₂ → H₃C-CH₃

This reaction is an example of an addition reaction, where atoms or molecules are added to the reactant molecule to form a product.

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do you expect keq to vary with increasing initial reactant concentration? group of answer choices yes, keq will increase with an increase in initial reactant concentrations yes, keq will decrease with an increase in initial reactant concentrations no, keq will not vary with initial reactant concentrations the answer depends on the reaaction

Answers

Equilibrium constant will not vary with initial concentration. The value of equilibrium constant depends on temperature and the enthalpy of the reaction. So the correct option from the following is option (c).

The equilibrium constant for a reversible chemical reaction is defined as the ratio of the concentrations when chemical equilibrium is reached and expresses the extent to which equilibrium of the reaction. It is the value of the reaction quotient of the chemical reaction at chemical equilibrium which signifies a state approached by a dynamic chemical system after the certain time has elapsed at which the composition of the reaction has no predictable tendency towards further change. The equilibrium concentrations of reactants and products of the chemical reaction depends on the initial concentrations but the value of Keq does not depends on it.

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The complete question is,

Do you expect Keq to vary with increasing initial reactant concentration?

Group of answer choices

A. Yes, Keq will increase with an increase in initial reactant concentrations

B. Yes, Keq will decrease with an increase in initial reactant concentrations

C. No, Keq will not vary with initial reactant concentrations

D. The answer depends on the reaction

how many times greater is the rate of effusion of molecular fluorine than that of molecular bromine at the same temperature and pressure? group of answer choices 3.062 2.051 4.450 7.280

Answers

The rate of effusion of molecular fluorine is 2.05 times than that of molecular bromine at the same temperature and pressure.

The rate of effusion of gas can be calculated by using Graham's Law.

According to this law, the rate of effusion of gas is inversely proportional to the square root of the molar mass of the gas.

The mathematical expression is represented as:

Rate of effusion ∝ [tex]\frac{1}{\sqrt{molar mass of the gas} }[/tex]

We know that,

Molar mass of bromine = 160 g/mol

Molar mass of fluorine =38 g/mol

For the rate of effusion of bromine to fluorine, the expression is given as:

[tex]\frac{rate of Fluorine gas}{rate of bromine gas} =\sqrt{\frac{molar mass of bromine gas}{molar mass of fluorine gas} }[/tex]

[tex]\frac{rate of Fluorine gas}{rate of bromine gas} =\sqrt{\frac{160}{38} }[/tex]= 2.05

Thus, the rate of effusion of fluorine is 2.05 times than that of bromine.

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Imagine you have three tuning forks of frequencies 250, 500 and 1000 Hz. Which one would:
A) sound the lowest
B) have the highest pitch

Answers

If we have three tuning forks of frequencies 250, 500 and 1000 Hz then the tuning fork of 250 Hz would sound the lowest and the tuning fork of 1000 Hz would have the highest pitch.

A.) The tuning fork of 250 Hz would sound the lowest, as it has the lowest frequency among the three. Frequency measures the number of oscillations per second of a wave so the 250 Hz wave will have fewer oscillations per second than the 500 Hz and 1000 Hz waves, resulting in a lower pitch. A lower frequency means that the sound waves are closer together, producing a lower, deeper sound.

B) The tuning fork of 1000 Hz would have the highest pitch, as it has the highest frequency. The 1000 Hz wave will have more oscillations per second than the 250 Hz and 500 Hz waves, resulting in a higher pitch. A higher frequency means that the sound waves are farther apart, producing a higher, more piercing sound.

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If 4.0 moles of CO2 and 2.5 moles of O2 are in a 25.5 Liter tank together,
how many more moles must be added to achieve a volume of 32.1 Liters?

Answers

We can use the combined gas law to solve this problem. Assuming that the pressure and temperature remain constant, we can use the following formula:

(P1 x V1) / n1 = (P2 x V2) / n2

where P1, V1, and n1 are the initial pressure, volume, and number of moles of the gas, and P2, V2, and n2 are the final pressure, volume, and number of moles of the gas.

Substituting the given values, we get:

(1 atm x 25.5 L) / (4.0 mol + 2.5 mol) = (1 atm x 32.1 L) / n2

Simplifying this equation, we get:

n2 = (1 atm x 32.1 L x (4.0 mol + 2.5 mol)) / (1 atm x 25.5 L) = 6.34 mol

Therefore, we need to add 6.34 - (4.0 mol + 2.5 mol) = 0.84 moles of gas to the tank to achieve a volume of 32.1 liters.

when the following equation is balanced properly under acidic conditions, what are the coefficients of the species shown? hno3 fe no fe2 water appears in the balanced equation as a fill in the blank 5 (reactant, product, neither) with a coefficient of . (enter 0 for neither.) how many electrons are transferred in this reaction?

Answers

Two electrons are transferred in this reaction

When answering questions on the platform Brainly, you should always be factually accurate, professional, and friendly. Additionally, you should be concise and do not provide extraneous amounts of detail. You should not ignore any typos or irrelevant parts of the question.

How to balance the equation HNO3 + Fe --> NO + Fe2+ under acidic conditions?In order to balance the equation HNO3 + Fe --> NO + Fe2+ under acidic conditions, follow the below steps:

First of all, write down the unbalanced equation:

HNO3 + Fe --> NO + Fe2+Add the coefficients to balance the iron atoms:

HNO3 + Fe --> NO + Fe2+Balance the hydrogen atoms by adding H+ ions on the left side:

HNO3 + Fe + H+ --> NO + Fe2+Add the electrons to balance the charges:

HNO3 + Fe + H+ + e- --> NO + Fe2+Now, add the electrons to the other side:

HNO3 + Fe + H+ + e- --> NO + Fe2+ + e-Balance the nitrogen atoms by adding H2O to the right side:

HNO3 + Fe + H+ + e- --> NO + Fe2+ + e- + H2OThe balanced equation is:

HNO3 + Fe + 3H+ + e- --> NO + Fe2+ + 2e- + H2O

What are the coefficients of the species shown in the balanced equation?The coefficients of the species shown in the balanced equation are as follows:

HNO3: 1Fe: 1H+: 3NO: 1Fe2+: 1H2O: 1

How many electrons are transferred in this reaction?

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A chemical reaction occurred when .500g of Calcium hydroxide falls into a 100ml of
8.5M hydroiodic acid.Is this enough calcium hydroxide to completely neutralize the all of the acid?

-How much salt forms in this reaction?

Answers

First, we need to determine the number of moles of hydroiodic acid in 100mL of 8.5M solution. Therefore, 1.98 g of calcium iodide forms in the reaction.

8.5 moles/L x 0.100 L = 0.85 moles of hydroiodic acid

Next, we need to determine the number of moles of calcium hydroxide used in the reaction.

0.500 g Ca(OH)2 x (1 mol Ca(OH)2/74.09 g) = 0.00674 moles Ca(OH)2

Since the stoichiometry of the reaction is 1:2 between Ca(OH)2 and HI, we need twice as many moles of hydroiodic acid to completely react with all the Ca(OH)2.

0.00674 moles Ca(OH)2 x 2 = 0.0135 moles HI needed

Since we have 0.85 moles of HI, which is more than enough to react with 0.0135 moles of Ca(OH)2, the reaction is complete.

To determine how much salt (calcium iodide) forms, we need to use the stoichiometry of the reaction, which is:

Ca(OH)2 + 2HI ⇒ CaI2 + 2H2O

Since two moles of hydroiodic acid react with one mole of calcium hydroxide to form one mole of calcium iodide, the amount of salt formed is:

0.00674 moles Ca(OH)2 x (1 mol CaI2/1 mol Ca(OH)2) = 0.00674 moles CaI2

Finally, we can calculate the mass of calcium iodide formed using its molar mass:

0.00674 moles CaI2 x 293.88 g/mol = 1.98 g CaI2

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a 10.0 ml of 0.121 m h2so4 is neutralized by 17.1 ml of koh solution. the molarity of the koh solution is . group of answer choices 0.428 m 0.207 m 0.0708 m 0.142 m 0.414 m

Answers

A 10.0 ml of 0.121 m [tex]H_2SO_4[/tex] is neutralized by 17.1 ml of [tex]KOH[/tex] solution. The molarity of the [tex]KOH[/tex] solution is:  0.142 M.

The correct answer choice is  " 0.142 m "

Balanced equation for the reaction is:

[tex]H_2SO_4[/tex] + 2[tex]KOH[/tex] → [tex]K_2SO_4[/tex]+ 2[tex]H_2O[/tex]

From the balanced equation, we can see that one mole of [tex]H_2SO_4[/tex] reacts with two moles of [tex]KOH[/tex].

Therefore, the number of moles of [tex]KOH[/tex] required to neutralize 10.0 ml of 0.121 M [tex]H_2SO_4[/tex] is:

0.121 moles/L × 10.0 mL × 1 L/1000 mL = 0.00121 moles

Since two moles of [tex]KOH[/tex] are required to react with one mole of [tex]H_2SO_4[/tex] , the number of moles of [tex]KOH[/tex] required is:

0.00121 moles [tex]H_2SO_4[/tex] × 2 moles [tex]KOH[/tex]/1 mole [tex]H_2SO_4[/tex] = 0.00242 moles [tex]KOH[/tex]

The volume of the [tex]KOH[/tex] solution required to supply 0.00242 moles [tex]KOH[/tex] is 17.1 mL.

Therefore, the molarity of the [tex]KOH[/tex] solution is:

0.00242 moles/17.1 mL × 1000 mL/1 L

= 0.142 M

Therefore, the correct answer choice is " 0.142 m "

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what is an intermediate in chemistry a point on the reaction pathway that has a discrete minima.

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An intermediate in chemistry is a substance that is generated in the middle of a chemical reaction and consumed after that point in the reaction pathway.

It can also be a point on the reaction pathway that has a discrete minimum value or point. An intermediate is generated during the rate-determining phase of a reaction, which is the slowest step in a reaction mechanism.

As a result, intermediates have a short lifespan since they are quickly converted to products.

The existence of intermediates is often demonstrated by kinetic studies, where a chemical reaction is observed over time. They are critical in organic chemistry because they can influence reaction rates and mechanisms.

Intermediates are usually unstable and reactive since they contain a high level of energy, making them susceptible to additional reactions leading to the products that are formed at the end of the reaction.

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a container with volume 71.9 ml contains water vapor at a pressure of 10.4 atm and a temperature of 465oc. how many grams of the gas are in the container?

Answers

The mass of the gas is 4.777 gram in the container with volume 71.9 ml contains water vapor at a pressure of 10.4 atm. and a temperature of 465 degree centigrade. This is calculated using ideal gas equation.

Volume of the water vapor = 71.9 ml = 0.0719L

Pressure of the water vapor = 10.4 atm.

Temperature of the water vapor =  465 degree C = 738 K

We can calculate the number of moles of water vapor by using the ideal gas equation.

    PV = n RT

10.4 atm. * 0.0719L = n * 8.314 J/ mole· K * 10.4 atm.

n = 10.4 atm. * 0.0719L  / 8.314 J/ mole· K * 10.4 atm.

   = 0.0086 mole

We know that the number of moles is equals to,

 Number of moles = mass / molar mass

                               = 0.0086 mole / 18 g/mole

                               = 4.777 g

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a voltaic cell is an electrochemical cell in which the redox reaction occurs non-spontaneously when an external power source is applied group of answer choices true false

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The given statement a voltaic cell is an electrochemical cell in which the redox reaction occurs non-spontaneously when an external power source is applied is false because an electrolytic cell requires an external power source to drive a non-spontaneous redox reaction.

A Voltaic cell, also known as a Galvanic cell, is an electrochemical cell in which the redox reaction occurs spontaneously, without the need for an external power source. The cell converts chemical energy into electrical energy as the reaction progresses. In contrast, an electrolytic cell requires an external power source to drive a non-spontaneous redox reaction. Hence the statement is false.

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it required 10.00 ml of 0.250 m naoh to titrate 50.00 ml of h 2 so 4 (to the equivalence point). what was the original concentration of the h 2 so 4 ?

Answers

The equivalent point of the HBr calculated by using the process of titration is 28 ml.

The term Titration is defined as the process which involves the slow addition of one solution of a known concentration which is called as a titrant added to a known volume of another solution of unknown concentration until the reaction reaches to the neutralization point. It is indicated by a color change. This common laboratory method of quantitative chemical analysis which is used to determine the concentration of an identified analyte of the solution. Titrant or titrator is the reagent which is prepared as a standard solution of known concentration and volume of the solution.

Molarity of the acid is 0.140 M

Volume of acid is 40 mL

Molarity of base is 0.200 M

We have the expression for the Molarity,

M1 V1 = M2 V2

V2 = M1 V1/ M2

by putting all the values in the expression we get,

V2 = 28 ml

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The correct question is,

What volume (in mL ) of 0.200M sodium hydroxide do we need to titrate 40.00 mL of 0.140   M HBr to the equivalence point?

calculate the solubility product constant, ksp for copper (i) chloride given that the solubility of this compound at 25c is 1.08 x 10^-2 g cucl in 100. g of water

Answers

The solubility product constant, ksp for copper (i) chloride given that the solubility of this compound at 25c is 1.08 x 10⁻²g cucl in 100. g of water is equals to the CuCl is 1.16 × 10⁻⁴.

The solubility product of a compound is calculated by the product of the powers of the concentration of ions of the corresponding compounds. When a compound is dissolved in any solvent, then one common ion should be present in the solvent and that compound. We have, Solubility of compound in CuCl

= 1.08 × 10⁻² g

temperature, t = 25°C

quantity of water = 100g

Solubility product constant formula, Ksp = [products]/[reactants]

The ksp for copper (i) chloride in CuCl

= s² = ( 1.08 × 10⁻² )²

= 1.16 × 10⁻⁴

Hence, required constant value is 1.16 × 10⁻⁴.

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the solubility product of ag2cro4 is 9.0 x 10^-12. explain the difference between the equilibrium postion attained when silver chromate is added to pure water and when it is added to 0.100 m agno3

Answers

The equilibrium position attained when Ag2CrO4 is added to a solution of 0.100 M AgNO3 will be shifted towards the dissolution of the solid compound.

How can we determine equilibrium position?

The solubility product constant (Ksp) of Ag2CrO4 is a measure of the tendency of the solid compound to dissolve into its constituent ions.

It can be expressed as the product of the concentrations of the ions involved in the equilibrium of the dissolution of the solid compound.

When Ag2CrO4 is added to pure water, it will dissolve slightly to form some Ag+ and CrO42- ions, and the system will reach an equilibrium state.

The equilibrium position will be such that the product of the concentrations of these ions is equal to the Ksp of the compound.

At this point, the rate of dissolution of the solid compound will be equal to the rate of precipitation of the solid compound.

On the other hand, when Ag2CrO4 is added to a solution of 0.100 M AgNO3, the concentration of Ag+ ions in the solution is much higher than in pure water.

This will shift the equilibrium position towards the side of the reaction that consumes the excess Ag+ ions.

In other words, more Ag2CrO4 will dissolve to form Ag+ and CrO42- ions, in order to consume the excess Ag+ ions in solution.

This will result in a lower concentration of Ag2CrO4 in the solution compared to when it is added to pure water.

Therefore, the equilibrium position attained when Ag2CrO4 is added to a solution of 0.100 M AgNO3 will be shifted towards the dissolution of the solid compound.

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Find the area of the shaded region of the trapezoid. A. 364 sq. units B. 130 sq. units C. 429 sq. units D. 663 sq. units

Answers

the area of the shaded region of the trapezoid.  is 270 - 45 = 225 sq. units. Thus, the answer is option A which is 225 sq. units.

To find the area of the shaded region in the trapezoid, we need to subtract the area of the smaller triangle from the area of the larger triangle. The height of both triangles is the same, so we only need to find the bases.

The base of the larger triangle is the sum of the bases of the trapezoid, which is 15 + 30 = 45 units. The height of the triangle is 12 units, so the area of the larger triangle is (1/2) x 45 x 12 = 270 sq. units.

To find the base of the smaller triangle, we need to subtract the length of the shorter base of the trapezoid (15 units) from the longer base (30 units) and divide by 2. So, the base of the smaller triangle is (30 - 15)/2 = 7.5 units. The area of the smaller triangle is (1/2) x 7.5 x 12 = 45 sq. units.

Therefore, the area of the shaded region is 270 - 45 = 225 sq. units. Thus, the answer is option A which is 225 sq. units.

The correct question is :

Find the area of the shaded region of the trapezoid.

A. 225  sq. units

B. 130 sq. units

C. 429 sq. units

D. 663 sq. units

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How are these words related?



dozen

gross

ream

decade
A)Units of time
B)Units of ordering
C) Involved counting things
Please answer ASAP

Answers

c. involved counting things.

involved counting things

olive oil is a liquid , so it contains mostly unsaturated fatty acids. these fatty acids have choose... intermolecular forces and choose... melting points.

Answers

Fatty acids are essential components of lipids and play an important role in the structure and function of biological membranes that are related to presence of double bonds in the hydrocarbon chains of unsaturated fatty acids.

Unsaturated fatty acids have weaker intermolecular forces than saturated fatty acids, which means that they have lower melting points. This is because unsaturated fatty acids have one or more double bonds in their hydrocarbon chains, which introduce kinks in the chains and prevent them from packing closely together. As a result, unsaturated fatty acids have more disordered and loosely packed structures, which makes them more prone to breaking apart and melting at lower temperatures compared to saturated fatty acids with stronger intermolecular forces and higher melting points.

Therefore, olive oil, which contains mostly unsaturated fatty acids, has weaker intermolecular forces and lower melting points than a solid fat like butter, which contains mostly saturated fatty acids.

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in class, we examined the change in the uv-vis spectrum for pt3-tpd as a function of temperature as shown by the repeat unit structure and spectra below. explain: what is causing the absorption at ca. 500 nm. what is causing the absorption to evolve at 600 to 625 nm. why the spectra cross at ca. 530 nm

Answers

At low temperatures, the HOMO→LUMO transition has a higher absorption, while the interligand transition has a lower absorption. However, as the temperature increases, the interligand transition becomes more significant, and the absorption peak shifts to longer wavelengths. When the HOMO→LUMO and interligand transitions are about the same, they cross, which causes the spectra to cross at around 530 nm.

As part of your class work, you examined the change in the UV-Vis spectrum for Pt3-TPD. A repeat unit structure and spectrum were used to represent the changes that occurred as the temperature varied. Based on this information, you need to explain what is causing the absorption at around 500 nm, what causes the absorption to evolve between 600-625 nm, and why the spectra cross at about 530 nm.The absorption at around 500 nm is caused by the HOMO→LUMO transitions of the Pt3-TPD oligomers. HOMO and LUMO are molecular orbitals that are related to the highest occupied molecular orbital and the lowest unoccupied molecular orbital, respectively. When an electron in the highest occupied molecular orbital (HOMO) is excited to the lowest unoccupied molecular orbital (LUMO) by the absorption of light at around 500 nm, this transition leads to absorption at this wavelength. The LUMO state of Pt3-TPD is primarily a delocalized π-π* state that is influenced by the phenyl rings that are substituted onto the TPD ligand. The absorption at this wavelength is also influenced by the arrangement of the chromophores in the Pt3-TPD oligomers.The absorption that occurs between 600-625 nm is due to the interligand transitions in Pt3-TPD oligomers. The Pt3-TPD oligomers contain pi-stacked chromophores that are closely linked together. When an electron in one chromophore is excited by the absorption of light, it causes a change in the energy level of the other chromophores, resulting in absorption in the 600-625 nm range. The absorption peak in this range becomes sharper and more well-defined as the temperature rises because it corresponds to intermolecular pi-stacking.The spectra cross at around 530 nm due to the overlap of the HOMOLUMO and interligand transitions.

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What does it do in reaching the transition state (which marks the activation energy necessary to promote the reaction?

Answers

The transition state in a chemical process is where the energy level is at its highest. The activation energy is the name given to this force. When two or more molecules are combined, collisions will occur.

They will react and produce new molecules if they strike with sufficient energy to pass through the transition state. The kinetics of a reaction are determined by the activation energy, the greater the energy hill, the slower the process. Energy is needed to form bonds, and energy is released when bonds are broken. In one reaction energy profile, the transition state is at its greatest point. Energy increases before the transition stage, which suggests the transition state absorbs energy.

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if the concentration of 1-iodopropane doubles and the concentration of sodium hydroxide quadruples in this sn2 reaction, how much faster is the reaction rate? ch7 d2 q1.pdf

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The concentration of 1-iodopropane doubles and the concentration of sodium hydroxide quadruples, the reaction rate of this SN2 reaction is 8 times faster.

To determine how much faster the reaction rate is when the concentration of 1-iodopropane doubles and the concentration of sodium hydroxide quadruples in this SN2 reaction, follow these steps:

1. Recall the rate law for an SN2 reaction:

rate = [tex]k[A][B][/tex], where k is the rate constant, and [A] and [B] represent the concentrations of the two reactants.

2. Let the initial concentrations of 1-iodopropane and sodium hydroxide be [A] and [B], respectively. Then, the initial reaction rate is:

Initial rate = [tex]k[A][B][/tex].

3. Now, the concentration of 1-iodopropane doubles (2[A]) and the concentration of sodium hydroxide quadruples (4[B]).

4. Calculate the new reaction rate with these adjusted concentrations:

New rate = [tex]k(2[A])(4[B]) = 8k[A][B][/tex].

5. To find how much faster the reaction rate is, divide the new rate by the initial rate:

(new rate / initial rate) =  [tex]\frac{(8k[A][B])}{(k[A][B])}[/tex].

6. Simplify the expression:

[tex]\frac{(8k[A][B])}{(k[A][B])}=8[/tex]

So, when the concentration of 1-iodopropane doubles and the concentration of sodium hydroxide quadruples, the reaction rate of this SN2 reaction is 8 times faster.

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When 1.00g of nylon is burnt in excess oxygen, it produces 2.50g of carbon dioxide. What is the percentage of carbon in nylon?

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The mass percentage of carbon in nylon is approximately 68.1%.

What is mass of carbon?

The first step is to calculate the amount of carbon in 2.50g of carbon dioxide, using the molar mass of carbon and carbon dioxide:

1 mole of carbon has a mass of 12.01g

1 mole of carbon dioxide has a mass of 44.01g (12.01g for carbon + 2(16.00g) for oxygen)

So, the mass of carbon in 2.50g of carbon dioxide is:

(12.01g / 44.01g) x 2.50g = 0.681g

This means that the original 1.00g of nylon must have contained 0.681g of carbon. To find the percentage of carbon in nylon, we divide the mass of carbon by the mass of nylon and multiply by 100:

(0.681g / 1.00g) x 100% = 68.1%

Therefore, the percentage of carbon in nylon is approximately 68.1%.

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Complete question is: When 1.00g of nylon is burnt in excess oxygen, it produces 2.50g of carbon dioxide. the percentage of carbon in nylon is approximately 68.1%.

a student obtained a wet burette from the cart but failed to rinse it with a small amount of the base before starting a titration. will more or less titrant (base) be required to neutralize the acid?

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The student failed to rinse a wet burette with a small amount of base before starting a titration. The student would need more titrant (base) to neutralize the acid than if they had rinsed the burette before starting the titration.

The reason for this is that when a wet burette is not rinsed with the titrant, the remaining water in the burette can dilute the titrant, thereby decreasing its concentration. If the titrant is diluted, more of it would be required to neutralize the same amount of acid. This would result in a titration that requires more titrant (base) to neutralize the acid than if the burette had been properly rinsed with the base.
In other words, not rinsing the burette with a small amount of base can affect the accuracy of the titration results. It is, therefore, important to properly rinse the burette with the titrant before starting a titration to avoid diluting the titrant and ensure accurate titration results.
In conclusion, more titrant (base) would be required to neutralize the acid if a wet burette is not rinsed with a small amount of base before starting a titration. It is essential to rinse the burette before starting a titration to avoid dilution of the titrant and ensure accurate titration results.

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What are the differences between Alkane and Alkyl radicals?

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Answer:

Alkanes are hydrocarbons with only single bonds between carbon atoms, while alkyl radicals are highly reactive species that contain a single unpaired electron and are formed when an alkane loses a hydrogen atom. Alkyl radicals are therefore not stable on their own and tend to quickly react with other molecules, while alkanes are relatively stable and unreactive.

Explanation:

Many movies show people tapping SOS on water pipes to get help. Why is tapping on water pipes a quicker way of passing on a message than yelling?

(Use science terminology)

Answers

Tapping on water pipes is a quicker way of passing on a message than yelling because of the difference in the speed of sound in water compared to air.

What is sound?

Sound travels faster in water than in air, with a speed of approximately 1,500 meters per second in water and 340 meters per second in air. When someone taps on a water pipe, the vibrations travel through the water faster than if they were to yell or shout. These vibrations can be detected by someone listening with their ear or using specialized equipment, allowing for the SOS message to be transmitted over a greater distance and more quickly than if the message were shouted. This phenomenon is due to the fact that water molecules are more tightly packed than air molecules, allowing sound waves to travel more efficiently through water.

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Complete question is: Many movies show people tapping SOS on water pipes to get help. Tapping on water pipes is a quicker way of passing on a message than yelling because of the difference in the speed of sound in water compared to air.

The system: N2O (g) + NO2(g)

3 NO (g) is at equilibrium. You add some NO2 and allow the system to adjust to the change. For each substance, indicate whether the amount of that substance present has increased, decreased or not changed when compared to the amount present in the original equilibrium.

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When [tex]NO2[/tex] is added to the system, according to Le Chatelier's principle, the equilibrium will shift to counteract the increase in[tex]NO2[/tex]. The reaction will proceed in the forward direction to consume the excess [tex]NO2[/tex].

As a result, the amount of [tex]N2O[/tex] will decrease, the amount of [tex]NO2[/tex] will decrease, and the amount of[tex]NO[/tex]will increase. The equilibrium will shift to the right to maintain a constant value of Kc.

Therefore, the amount of [tex]N2O[/tex] and [tex]NO2[/tex]will decrease, and the amount of [tex]NO[/tex] will increase. This is because the forward reaction [tex](N2O + NO2 = 3NO)[/tex]will consume the added[tex]NO2[/tex], which will cause the amount of[tex]N2O[/tex]to decrease. In response, the reverse reaction [tex](3NO → N2O + NO2)[/tex]will proceed, causing the amount of [tex]NO[/tex] to increase. The equilibrium will shift in the forward direction to restore the balance between the reactants and products.

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all of the following are true of acid-base neutralization, except: select the correct answer below: a strong acid combined with a strong base, in stoichiometrically equal amounts, will always form a neutral solution. the combination of a weak acid with a weak base in stoichiometrically equal amounts can yield either an acidic, basic, or neutral solution. a strong acid combined with a weak base in stoichiometrically equal amounts yields an acidic solution a neutral solution is always formed when stoichiometrically equivalent amounts of an acid and a base are mixed.

Answers

A. Strong acids and bases effectively cancel each other out when combined in an equal proportion, yielding salt and water. A solution with a neutral pH (pH = 7) is also created by combining an equal amount of a strong acid and a strong base. We refer to this as a neutralizing reaction.

B. The conjugate base of the weak acid is a weak base, though, and it hardly ionizes in water. This makes the solution somewhat basic and increases the quantity of hydroxide ion generated by the process in it. It is possible to create an acidic, basic, or neutral solution by mixing a weak acid and a weak base.

c. A weakly acidic solution is produced when a strong acid and weak base are combined. This is not due of the strong acid itself, but rather because of the conjugate acid of the weak base.

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how many milliliters of cobalt(ii) chloride hexahydrate solution were added to the flask (before dilution)? note: the volume of substances dispensed in the lab may vary. choose the answer that is closest to yours.

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The volume of CoCl ₂ needed before dilution is 10.0 mL. Hence, the right answer is 10.0 mL.

As per the given problem; Calculate the volume of 0.100 M CoCl ₂ needed to prepare 100.0 mL of 0.0100 M CoCl ₂ solution.

The molarity of the diluted solution (after adding water) is M2 = 0.0100 M,

the volume of the diluted solution is V2 = 100.0 mL,

and the molarity of the stock solution is M1 = 0.100 M.

The volume of the stock solution needed is given by the equation below:

M1V1 = M2V2⇒V1= M2V2/M1⇒V1

= 0.0100 M x 100.0 mL/0.100 M⇒V1

= 10.0 mL

Therefore, we need 10.0 mL of 0.100 M CoCl ₂ solution to prepare 100.0 mL of 0.0100 M CoCl ₂ solution before dilution. So, the volume of CoCl ₂ needed before dilution is 10.0 mL.

Hence, the right answer is 10.0 mL.

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