consider the molecule h79br and its isotopic exchanged molecules, deuterated molecule d79br and bromine exchanged molecule h81br. using the bond length of h79br calculated in previous question, compute the change in rotational constant for the other two molecules. briefly comment on how isotopic exchange changes the rotational spectra. does the exchange of 1 h or 79br have a greater effect?

The restricting reactant is the reactant that is totally consumed in the reaction, thereby restricting how much item that can be shaped. To decide the restricting reactant, we want to look at how much every reactant present to the stoichiometric ratio of the reasonable chemical equation.

In this case, the decent chemical equation is:

2Al(s) + 3Cu(NO3)2(aq) → 3Cu(s) + 2Al(NO3)3(aq)

From the equation, we can see that the stoichiometric ratio of aluminum to copper(II) nitrate is 2:3. This means that for each 2 moles of aluminum, we want 3 moles of copper(II) nitrate to totally respond.

Based on the given information, aluminum is the restricting reactant because it is totally consumed in the reaction, while copper(II) nitrate remains in the solution. This is indicated by the colorless solution of aluminum nitrate shaped, which indicates that all of the copper(II) nitrate has responded with aluminum to frame copper metal and aluminum nitrate.

Therefore, the right answer is Aluminum, because it was totally consumed in the reaction.

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Hydrogen should show more lines in the visible spectrum compared to lithium if all possible transitions occur.

The number of spectral lines in the visible spectrum of an element depends on the energy levels and electron transitions within that element. In general, the number of lines in an element's spectrum is related to the complexity of its atomic structure.

Lithium (Li) has a simpler atomic structure compared to hydrogen. Hydrogen has more energy levels and a greater number of possible electron transitions, resulting in a more complex spectrum with a larger number of spectral lines. Therefore, assuming all possible transitions occur, the visible spectrum of hydrogen would generally show more lines than the visible spectrum of lithium.

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The repeat unit of the addition polymer that can be formed from Pent-4-enoic acid is shown below:

      H    H

      |      |

H₂- C = C-C(CH₂)₂COOH

       |     |

      H    H

Since polymer molecules are much larger than most other molecules, the concept of a repeat unit is used when drawing a displayed formula.

When creating one, change the monomer's double bond to a single bond in the repeat unit, and add a bond to each end of the repeat unit. At the end, put the letter n in subscript after the brackets (n represents a very large number of the repeating unit)

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The mole fraction of salt in a solution of saltwater with a molality of 3.24 m is 0.764.

Molality is a measure of concentration used in chemistry. Molality is a measure of the amount of solute dissolved in a certain quantity of solvent, usually measured in moles per kilogram. Mole fraction is a measure of the amount of solute present in a solution. The mole fraction of a component in a solution is given by the number of moles of that component divided by the total number of moles of all the components present in the solution.

Mole fraction can be calculated using the following formula:

Xsolute = nsolute / ntotal

where, Xsolute = mole fraction of the solute, n solute = number of moles of the solute, n total = total number of moles of all the components in the solution

Given that the molality of saltwater is 3.24 m. This means that 3.24 moles of salt are present in 1 kg of water. Therefore, the total number of moles of all the components present in the solution is:

n total = 3.24 + 1.00 = 4.24 moles. The mole fraction of salt in the solution is given by:

nsolute / ntotal = 3.24 / 4.24 = 0.764

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a. the number of moles of carbon monoxide is  39.21875 mol CO

b. the pressure of CO in a 1.00 L container at 5000°C is 178,426 atm.

c. the volume occupied by 39.21875 moles of CO at standard pressure (101.3 kPa) and 5000°C is 17,706 L.

The given chemical equation is incorrect as it shows the production of carbon monoxide (CO) which is not produced in the reaction of TNT. The correct equation for the decomposition of TNT is:

2 C7H5N3O6 -> 3 N2 + 5 H2O + 7 CO

a. Calculate the number of moles of carbon monoxide produced if 2550 grams of TNT decomposes according to the equation above.

Molar mass of TNT = (2 x 12.01) + (7 x 1.01) + (3 x 14.01) + (6 x 16.00) = 227.13 g/mol

Number of moles of TNT = 2550 g / 227.13 g/mol = 11.225 mol

From the balanced equation, 7 moles of CO are produced for every 2 moles of TNT. Therefore, the number of moles of CO produced will be:

11.225 mol TNT x (7 mol CO / 2 mol TNT) = 39.21875 mol CO

b. In a 1.00 L container, what would be the pressure of this many moles of CO at 5000°C?

We can use the Ideal Gas Law to determine the pressure of CO at 5000°C:

PV = nRT

where P is the pressure, V is the volume, n is the number of moles, R is the gas constant, and T is the temperature in Kelvin.

Since the volume is given as 1.00 L, we can convert the temperature to Kelvin:

5000°C + 273.15 = 5273.15 K

The gas constant is R = 0.08206 L•atm/(mol•K).

Substituting the values into the Ideal Gas Law and solving for P:

P = nRT/V = (39.21875 mol)(0.08206 L•atm/(mol•K))(5273.15 K)/1.00 L = 178,426 atm

Therefore, the pressure of CO in a 1.00 L container at 5000°C is 178,426 atm.

c. What volume would be occupied by this number of moles at standard pressure (101.3 kPa) and 5000°C?

To determine the volume occupied by 39.21875 moles of CO at standard pressure and 5000°C, we can use the Ideal Gas Law again, but this time with the pressure and temperature given in standard units:

P = 101.3 kPa = 1.00 atm

T = 5000°C + 273.15 = 5273.15 K

Substituting these values and solving for V:

V = nRT/P = (39.21875 mol)(0.08206 L•atm/(mol•K))(5273.15 K)/(1.00 atm) = 17,706 L

Therefore, the volume occupied by 39.21875 moles of CO at standard pressure (101.3 kPa) and 5000°C is 17,706 L.

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Approximately 402.27 grams of sodium azide (NaN₃) must decompose to fill a 55.0-gallon airbag.

The ideal gas law is a fundamental equation that describes the behavior of ideal gases under a wide range of conditions. It relates the pressure (P), volume (V), temperature (T), and number of moles of gas (n) of an ideal gas through the equation:

PV = nRT

where R is the gas constant, which has a value of 8.314 J/(mol·K) or 0.0821 L·atm/(mol·K) in SI units.

We know that the volume of the airbag is 55.0 gallons, so we need to convert this to liters using a conversion factor.

1 gallon = 3.78541 liters

Therefore, the volume of the airbag in liters is:

55.0 gallons x 3.78541 liters/gallon = 208.20 liters

Next, we need to calculate the number of moles of N₂ gas that would be produced from the decomposition of NaN₃ required to fill the airbag.

From the balanced equation:

2 NaN₃ (s) -> 2 Na (s) + 3 N₂ (g)

We can observe that two moles of NaN₃ result in three moles of N₂. Therefore, the number of moles of N2 produced is:

moles of N2 = (2/3) x moles of NaN₃

To fill the airbag, we need enough N₂ gas to occupy a volume of 208.20 liters. One mole of any gas has a volume of 22.4 litres at standard temperature and pressure (STP).

Therefore, the number of moles of N₂ required is:

moles of N₂ = (208.20/22.4) = 9.29 moles

Now we can use the balanced equation to calculate the number of moles of NaN₃ required:

2 NaN₃ (s) -> 2 Na (s) + 3 N2 (g)

For every 3 moles of N₂ produced, we need 2 moles of NaN3. Therefore, the number of moles of NaN₃ required is:

moles of NaN₃ = (2/3) x moles of N₂ = (2/3) x 9.29 = 6.19 moles

Finally, we can use the molar mass of NaN₃ to calculate the mass required:

mass of NaN₃ = moles of NaN₃ x molar mass of NaN₃

The molar mass of NaN₃ is:

Molar mass of NaN₃ = (1 x 22.99) + (3 x 14.01) = 65.01 g/mol

Therefore, the mass of NaN₃ required to fill the airbag is:

mass of NaN₃ = 6.19 moles x 65.01 g/mol = 402.27 grams

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Answer:

0.56 mi/hr

Explanation:

hope this helps

When filling a burette for a titration, adjust the burette so that the tip is located slightly below the level of the meniscus, preferably over a sink. Then, use a funnel to add the titrant into the burette. The titrant should be filled above the 0.00 mL line.

A burette is a laboratory equipment that is used to dispense known volumes of liquid in experimental procedures. It is usually made of glass and has a long, cylindrical shape with a stopcock at the bottom to control the flow of liquid.

Burettes are commonly used in titration experiments to accurately measure the volume of the titrant added to the sample. Adjust the burette so that the tip is located slightly below the level of the meniscus, preferably over a sink. This is to prevent the loss of any of the titrant that may overflow. Using a funnel, carefully add the titrant into the burette. Make sure to pour the titrant slowly to avoid splashing or spilling any of it. The titrant should be filled above the 0.00 mL line.

This allows the initial volume of the titrant to be measured accurately before titration commences. If there are air bubbles present, they should be removed by gently tapping the burette.

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The condensation (dehydrated) product rather than the aldol addition (hydrated) product obtained in this experiment is due to the greater stability of the condensation product.

The aldehyde is dehydrated in the aldol condensation process to produce the β-hydroxyaldehyde which then eliminates a water molecule to form an α,β-unsaturated aldehyde or ketone. The condensation product is obtained rather than the aldol addition product in this experiment due to the greater stability of the condensation product. The condensation product is exceptionally stable due because the resonance stabilization. In the condensation product, the carbonyl group in the β position is connected to the α-carbon through a double bond. The carbon-carbon double bond is delocalized over the two carbon atoms in the compound, and this contributes to the overall stability of the compound.

Chelation effect, the carbonyl group in the β position is also involved in chelation with the metal ion. As a result, the overall stability of the compound is increased. Elimination of the water molecule: In the aldol reaction, the product of the reaction has a water molecule in it. This water molecule is eliminated during the condensation reaction, which leads to an increase in the stability of the compound.

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There are approximately 11.78 grams of oxygen gas (O2) in 8.25 L at STP.

To calculate the number of grams of oxygen gas (O2) in 8.25 L, we need to use the ideal gas law which states:

PV = nRT

Where;

Assuming standard temperature and pressure (STP) conditions (0°C and 1 atm), we can use the molar volume of a gas at STP, which is 22.4 L/mol, to calculate the number of moles of oxygen gas in 8.25 L:

n = (V / V_m) = (8.25 L) / (22.4 L/mol) = 0.3683 mol

The molar mass of O2 is approximately 32 g/mol, so we can calculate the number of grams of oxygen gas in 0.3683 mol:

mass = n x molar mass = 0.3683 mol x 32 g/mol = 11.78 g

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Among the given options, the element that requires the most energy to lose one electron is option B) Ca2+.

This is because, in Ca2+, the electron is removed from an inner shell, which requires more energy than removing an electron from the outer shell. The outermost electron shell of Ca2+ is already filled with electrons, so the next electron is in an inner shell, which is tightly bound to the nucleus. Therefore, it requires more energy to remove this electron than it does to remove an electron from an outer shell.

The other options listed are:

A) Li: Lithium has a single electron in its outer shell, so it is relatively easy to remove an electron from it.

C) Si2+: Silicon has four electrons in its outer shell, so it requires less energy than Ca2+ to remove one electron.

D) P: Phosphorus has five electrons in its outer shell, so it requires less energy than Ca2+ to remove one electron.

E) Na: Sodium has a single electron in its outer shell, so it requires less energy than Ca2+ to remove one electron.

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Answer:

The mass of lithium hypochlorite are 34.7 grams.

Explanation:

Moles of = 0.594 g. Molar mass of = 58.4 g/mol.

The gas that diffuses the fastest under the same conditions is He. The correct answer is Option D.

Diffusion is the process by which molecules move from high concentrations to low concentrations. The rate at which diffusion occurs is determined by the type of gas or vapor, temperature, and pressure. In a gas, the rate of diffusion is proportional to the mean free path of its molecules, which in turn is proportional to the square root of its absolute temperature.

Helium (He) is a chemical element with atomic number 2 and symbol He. It is a colorless, odorless, tasteless, non-toxic, inert monatomic gas that heads the noble gas group in the periodic table of elements. Its boiling and melting points are the lowest of any substance, and it exists just as a gas other than a very small liquid state in a closed cell. It's the second-most abundant element in the universe, after hydrogen. Helium is also a valuable gas, and its use in cryogenics and deep-sea diving has expanded in recent years.

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Explanation:

The heat of fusion given has units of  kJ / MOL

  so we need to find the number of moles in 70 . 0 g

    using periodic table,    mole wt for AU =196.97 g/mol

     then 70 g   is   70 g / 196.97 g/mol = .355 mole

Now to MELT the gold     .355 mole * 12.5 kJ/mol = 4.44 kJ  ( = 4440 J)

Then to HEAT the liquid to 1213 degrees C from the melting point :

  70 g  * (1213 - 1063) C * .129 J / (g C) = 1355 J

Then add together   4.44kJ  + 1355 J = 4440 J + 1355 J = 5795 J

In glycolysis, ATP is consumed in the reaction producing fructose-1,6-bisphosphate, which is a crucial intermediate in the pathway and is required for the further breakdown of glucose to pyruvate. The correct answer is option: B.

Glycolysis is the process by which glucose is broken down into two molecules of pyruvate, which is a key step in cellular respiration. The process occurs in ten steps and involves the conversion of glucose to two molecules of pyruvate, with the concomitant production of ATP and NADH . During the third step of glycolysis, the enzyme phosphofructokinase catalyzes the conversion of fructose-6-phosphate to fructose-1,6-bisphosphate, consuming one molecule of ATP in the process. Option: B is correct.

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The order of reaction is 1 and the value of the rate constant is 6.74*10^-5s^-1.What is the order of the reaction? To solve this question we have to check the half-life of a chemical reaction at different concentrations.

It is given in the question that when the initial concentration of reactant is 0.154m, it has half-life of 103s. Similarly, when initial concentration is 0.664m, it has half-life of 103s. To find the order of reaction, we have to use the equation for half-life of reaction. The equation for half-life of reaction is given as:\[\frac{t_{1/2} }{2}=\frac{1}{k}\frac{1}{[A]_{0}}\]Where, t1/2 is half-life of the reaction,[A]0 is the initial concentration of the reactant and k is the rate constant.

Putting the values in equation: When [A]0 = 0.154m and t1/2 = 103s, we get:\[\frac{103}{2}= \frac{1}{k} \frac{1}{0.154}\] Multiplying both sides with 0.154k:\[k*\frac{103}{2}*0.154 = 1\]When [A]0 = 0.664m and t1/2 = 103s, we get:\[\frac{103}{2}= \frac{1}{k} \frac{1}{0.664}\]Multiplying both sides with 0.664k:\[k*\frac{103}{2}*0.664 = 1\]Dividing second equation by first equation:\[\frac{k*\frac{103}{2}*0.664}{k*\frac{103}{2}*0.154}= \frac{0.664}{0.154}\] Simplifying the above equation, we get:\[k=6.74*10^{-5}s^{-1}\]Therefore, the order of reaction  is 1 and the value of the rate constant is 6.74*10^-5s^-1.

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Two reasons why the iodination electrophilic aromatic substitution (EAS) reaction can be described as "green" are the Use of a benign solvent and Use of a less hazardous oxidant. Correct answers are option : 2 & 3.

The reaction uses a solvent, such as acetic acid, which is relatively non-toxic, biodegradable, and readily available, making it an environmentally friendly choice compared to more toxic and harmful solvents. Overall, the use of benign solvents and less hazardous oxidants reduces the environmental impact of the reaction and makes it more sustainable, earning it the label of a "green" reaction. Option 2 & 3 are correct.

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--The complete Question is, Choose two reasons that the iodination EAS reaction can be described as "green." Select one or more:
1. Use of renewable energy

2. Use of a benign solvent

3. Use of a less hazardous oxidant

4. Use of a catalyst ---

Radiation is the mechanism of heat transfer that does not need any medium. Hence, option C is correct.

Radiation is generally defined as the energy that comes from a source and travels through the space at the speed of light. This type of energy has an electric field and a magnetic field which is associated with it, and has wave-like properties. We can also call radiation as “electromagnetic waves”.

Generally, radiation is defined as the transfer of heat through electromagnetic waves through space. Unlike convection or conduction, in which energy produced from gases, liquids, and solids is transferred by the molecules with or without their physical movement, radiation does not need any medium (molecules or atoms). Hence, option C is correct.

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132.2 g of MgSO₄ contains 4.392 moles of oxygen ions.

To determine the number of moles of oxygen atoms in 132.2 g of MgSO₄, we need to first calculate the number of moles of MgSO₄, and then use its chemical formula to determine the number of oxygen atoms present.

The molar mass of MgSO₄ can be calculated by adding the atomic masses of its constituent elements, which are 24.31 g/mol for Mg, 32.06 g/mol for S, and 4x16.00 g/mol for O, respectively. Therefore, the molar mass of MgSO₄ is:

molar mass of MgSO₄ = 24.31 + 32.06 + 4(16.00) = 120.37 g/mol

Next, we can calculate the number of moles of MgSO₄ in 132.2 g as follows:

moles of MgSO₄ = mass of MgSO₄ / molar mass of MgSO₄

moles of MgSO₄ = 132.2 g / 120.37 g/mol

moles of MgSO₄ = 1.098 mol

Finally, we can use the chemical formula of MgSO₄ to determine the number of moles of oxygen atoms present in 132.2 g of MgSO4. The formula of MgSO₄ indicates that there are four oxygen atoms per molecule of MgSO₄. Therefore, the number of moles of oxygen atoms in 132.2 g of MgSO₄ is:

moles of oxygen atoms = moles of MgSO₄ x 4

moles of oxygen atoms = 1.098 mol x 4

moles of oxygen atoms = 4.392 mol

Therefore, there are 4.392 moles of oxygen atoms in 132.2 g of MgSO₄

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The fulminate ion has the chemical formula CNO-, and its Lewis structure can be drawn as follows:

Place the carbon atom in the center since it is the least electronegative atom among C, N, and O.

Connect the carbon atom to the nitrogen atom with a triple bond, as nitrogen is more electronegative than carbon.

Connect the nitrogen atom to the oxygen atom with a single bond since oxygen is more electronegative than nitrogen.

Add a lone pair of electrons to the oxygen atom to satisfy its octet.

Place a negative charge on the oxygen atom since it has gained an extra electron.

The Lewis structure with all atoms and bonds is as follows:

markdown

     O

     ||

C ≡ N -

     ||

     H

All atoms except for the nitrogen atom have a formal charge of 0. The nitrogen atom has a formal charge of +1 because it has four valence electrons but only three bonding electrons. The oxygen atom has a formal charge of -1 because it has six valence electrons but seven electrons around it.

The Lewis structure can also be represented by showing the possible resonance forms:

makefile

 O         O

 ||        ||

C = N  ↔  C ≡ N

 ||        ||

 H         H

In this case, the double bond is delocalized between the carbon and nitrogen atoms, and both resonance structures contribute to the overall electronic structure of the fulminate ion.

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Answer:

56.4 kJ

Explanation:

First, let's convert the mass of water from grams to moles. We can do this by dividing the mass by the molar mass of water, which is approximately 18 g/mol.

25 g ÷ 18 g/mol ≈ 1.39 mol

So we have 1.39 moles of water that we want to vaporize.

Next, we need to use the molar heat of vaporization to calculate how much energy is required to vaporize one mole of water. The molar heat of vaporization tells us how much energy is needed to vaporize one mole of a substance at a constant temperature and pressure. In this case, the molar heat of vaporization for water is 40.6 kJ/mol.

So, to vaporize 1 mole of water, we need 40.6 kJ of energy.

Finally, we can use this information to calculate how much energy is required to vaporize 1.39 moles of water. We can multiply the energy required to vaporize one mole of water by the number of moles we have:

40.6 kJ/mol × 1.39 mol ≈ 56.4 kJ

Therefore, it would take approximately 56.4 kJ of energy to vaporize 25 g of liquid water at 100°C.

I hope this explanation helps!

NqrB and NqrC are the two subunits of Na-NQR which can be separated by gel filtration but not by ion exchange chromatography.

The sodium-dependent NADH-quinone oxidoreductase (Na-NQR) is a membrane-bound enzyme complex found in bacteria that participates in the electron transport chain. It consists of six subunits: NqrA, NqrB, NqrC, NqrD, NqrE, and NqrF.

we need to consider the properties of the subunits and the mechanisms of the separation techniques. Gel filtration separates molecules based on their size, while ion exchange chromatography separates molecules based on their charge.

Based on this information, we can infer that the two subunits that can be separated by gel filtration but not by ion exchange chromatography are those that have similar sizes but different charges. Among the six subunits of Na-NQR, NqrB and NqrC are the two subunits that have similar molecular weights (~45 kDa) but different charges.

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Since the molar mass of the unknown gas is less than that of nitrogen or carbon dioxide, it is likely a lighter gas such as helium (He) or hydrogen (H₂).

Effusion rate of a gas is inversely proportional to the square root of its molar mass and therefore, we use Graham's law of effusion to determine the molar mass of unknown gas.

Let molar mass of CO be M₁ and molar mass of the unknown gas be M₂.

According to Graham's law of effusion: (rate of CO) / (rate of unknown gas) = √(M₂ / M₁)

So, (30.50 / 32.60) = √(M₂ / M₁)

(30.50 / 32.60)² = M₂ / M₁

M₂ = M₁ * (30.50 / 32.60)²

= 28 * (30.50 / 32.60)²

M2 = 25.4 g/mol

Therefore,  molar mass of the unknown gas is approximately 25.4 g/mol. Molar mass of nitrogen (N₂) is approximately 28 g/mol, and molar mass of carbon dioxide (CO₂) is approximately 44 g/mol. Since the molar mass of the unknown gas is less than that of nitrogen or carbon dioxide, it is likely a lighter gas such as helium (He) or hydrogen (H₂).

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3.33 grams of magnesium were utilized, and the same amount of magnesium chloride was generated.

One mole of magnesium interacts with two moles of hydrochloric acid to form one mole of magnesium chloride and one mole of hydrogen gas, as shown by the equation.

mass / molar mass equals moles of HCl.

The formula for HCl is 10.0 g/36.46 g/mol (molar mass of HCl)

HCl equals 0.274 moles per unit.

Mg = 0.274 moles and 2 moles of Mg are equal to 0.137 moles.

When 0.137 moles of HCl are added, the mass of magnesium needed is:

Mg mass is calculated as Mg moles times Mg molar mass.

Mg's mass is 3.33 g.

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meat cooking is a chemical change

Heating a meat changes its colour to brownish due to Maillard reaction

Answer:

Primary succession happens when a new patch of land is created or exposed for the first time.

Explanation:

The most water-soluble of the aforementioned chemicals is ethylene glycol (HOCH2 CH2 OH). Two of the hydroxy groups in ethylene glycol create hydrogen bonds with one another.

Water is a great solvent that can dissolve a wide variety of compounds due to its polarity and capacity to create hydrogen bonds. Because it is more polar than methane, methanol dissolves better in water. Water is polar, whereas methane is non-polar.

All salts of sodium, potassium, and ammonium are water soluble. 3. All metals, with the exception of lead, silver, and mercury(I), have chlorides, bromides, and iodides that are soluble in water. In water, HgI2 is insoluble.

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