The number of calories in 3 grams of peanuts, based on the given data, is approximately 10.88 calories. The correct answer is (c) 10.88 cal.
To calculate the number of calories in 3 grams of peanuts, we need to use the data collected from the experiment and apply the following formula:
calories = (mass of substance burned × specific heat of water × temperature change of water) ÷ volume of water
We are given that the mass of peanut burned was 0.75 g, the volume of water heated was 50 mL, and the temperature change of water was 14.5 °C.
The specific heat of water is 1 calorie per gram per degree Celsius (1 cal/g°C).
Substituting the given values into the formula, we get:
calories = (0.75 g × 1 cal/g°C × 14.5 °C) ÷ 50 mL
calories = 10.88 cal
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which of the following statements correctly describe protecting groups? select all statements that apply. multiple select question. a reactive functional group is converted into another functional group that does not interfere with the desired reaction. when the oh group of an alcohol is reacted with tbdmscl/imidazole the resulting tbdms ether is known as a protecting group. protecting groups must be easily removed (deprotection) to regenerate the original functional group.
The statements correctly describe protecting groups are :
"A reactive functional group converted to another functional group and it will not interfere desired reaction."
"The Protecting group easily removed (deprotection) to the regenerate original functional group."
The protecting group are the molecular formula that will be introduced the specific functional group and which is present in the poly-functional molecule and the protecting group block the reactivity under the some reaction conditions and which is needed to make the modifications in molecule.
The protecting group readily and the protecting group is selectively introduced to functional group in poly-functional molecule. Protecting group is capable of the selectively removed in under some of the mild conditions when protection is no more longer required.
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The ______ is the amount of a substance that dissolves in a given quantity of solvent at a particular temperature to produce a saturated solution
The solubility is the amount of a substance that dissolves in a given quantity of solvent at a particular temperature to produce a saturated solution.
Definition: Solubility is defined as the maximum amount of solute that can dissolve in a given quantity of solvent at a specific temperature and pressure to form a saturated solution. It is typically expressed in terms of the mass of solute per unit volume or mass of solvent.
Solute and Solvent: In a solution, the solute is the substance that is being dissolved, while the solvent is the medium in which the solute dissolves. The solute can be a solid, liquid, or gas, while the solvent is usually a liquid, but can also be a gas or a solid in some cases.
Saturated Solution: A saturated solution is a solution in which the maximum amount of solute has been dissolved in a given quantity of solvent at a specific temperature. In a saturated solution, the rate of dissolution of the solute is balanced by the rate of precipitation or crystallization of the solute, resulting in a dynamic equilibrium.
Factors Affecting Solubility: The solubility of a solute depends on several factors, including temperature, pressure, and the nature of the solute and solvent.
Generally, increasing temperature enhances solubility for most solid solutes, while the effect of pressure on solubility is more significant for gases dissolved in liquids. The polarity and intermolecular forces between the solute and solvent molecules also influence solubility.
Solubility Curves: Solubility can be represented graphically by constructing solubility curves. These curves depict the relationship between the solute's solubility and the temperature or pressure.
Solubility curves can help determine the maximum amount of solute that can dissolve under different conditions and can vary for different solutes and solvents.
Supersaturation: Under certain conditions, it is possible to create a supersaturated solution, where the solute concentration exceeds the solubility limit at a given temperature.
Supersaturated solutions are unstable and can result in the precipitation of excess solute upon the introduction of a seed crystal or disturbance.
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1.
What is the boiling point of a solution prepared by dissolving 2. 50 g of biphenyl (C12 H10)
in 85. 0 g of benzene. The molecular weight of biphenyl is 154 g.
The boiling point of the solution is 80.58 °C, which is prepared by dissolving 2. 50 g of biphenyl (C₁₂ H₁₀).
To determine the boiling point of the solution, we need to use the equation;
Δ[tex]T_b}[/tex] = [tex]K_{b}[/tex] x m
Where ΔTb is boiling point elevation, is molal boiling point elevation constant, and m is molality of the solution.
First, we to calculate the molality of the solution;
moles of biphenyl =2.50 g / 154 g/mol
= 0.0162 mol
mass of benzene = 85.0 g
moles of benzene = 85.0 g / 78.11 g/mol
= 1.088 mol
molality = moles of solute/mass of solvent (in kg)
molality = 0.0162 mol / 0.085 kg
= 0.19 mol/kg
Next, we need to look up the molal boiling point elevation constant ([tex]K_{b}[/tex]) for benzene. The value of [tex]K_{b}[/tex] for benzene is 2.53 °C/m.
Finally, we alculate the boiling point elevation;
Δ[tex]T_b}[/tex] = [tex]K_{b}[/tex] x m
Δ[tex]T_b}[/tex] = 2.53 °C/m x 0.19 mol/kg
= 0.481 °C
The boiling point elevation (Δ[tex]T_b}[/tex]) is the difference between the boiling point of the solution and the boiling point of the pure solvent. The boiling point of pure benzene is 80.1 °C. Therefore, the boiling point of the solution will be;
Boiling point of solution = 80.1 °C + 0.481 °C
= 80.58 °C
So, the boiling point of the solution is 80.58 °C.
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Help what’s the answer?
Consider the following reaction and its Δ at 25.00 C
Mg(s)+Ni2+(aq)⟶Mg2+(aq)+Ni(s)Δ∘=−408.0 kJ/mol
calculate the standard cell potential ∘cell, for reaction
∘cell=
calculate the equilibrium constant, K, for reaction
K=
The standard cell potential (∆°cell) can be calculated using the formula:
∆°cell = ∆°reduction (reduced) - ∆°oxidation (oxidized)
where ∆°reduction and ∆°oxidation are the standard reduction potentials of the reduction and oxidation half-reactions, respectively.
The oxidation half-reaction is:
Ni2+(aq) + 2e- → Ni(s) ∆°oxidation = - 0.26 V
The reduction half-reaction is:
Mg2+(aq) + 2e- → Mg(s) ∆°reduction = - 2.37 V
Therefore, the standard cell potential is:
∆°cell = ∆°reduction - ∆°oxidation
∆°cell = (-2.37 V) - (-0.26 V)
∆°cell = -2.11 V
The equilibrium constant (K) can be calculated from the standard cell potential using the Nernst equation:
∆°cell = -(RT/nF) ln K
where R is the gas constant (8.314 J/(mol·K)), T is the temperature in Kelvin (298 K), n is the number of electrons transferred in the balanced equation (2), and F is the Faraday constant (96,485 C/mol).
Substituting the values and solving for K, we get:
K = exp(-(∆°cell)/(RT/nF))
K = exp(-((-2.11 V)*(96,485 C/mol)/(8.314 J/(mol·K)298 K2)))
K = 1.1 × 10^12
Therefore, the equilibrium constant for the reaction is 1.1 × 10^12.
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Zinc reacts with HCl to produce hydrogen gas, H2, and ZnCl2.
Zn(s) + 2 HCl(aq) --> H2(g) + ZnCl2(aq)
How many liters of a 1.50 M HCl solution completely react with 5.32 g of zinc?
Answer:
0.108L HCl
Explanation:
5.32 g zinc * 1 mol zinc/65.38g zinc * 2 mol HCl/1 mol zinc * L HCl/1.5 mol HCl = 0.108L HCl
Please help!!! The following thermodynamically favored reaction takes place in an acidified
galvanic cell.
O2(g) + 2 H2S(g) 2 S(s) + 2 H2O(l)
a. What is the half reaction that takes place at the anode?
b. What is the half reaction the takes place at the cathode?
c. Calculate the standard cell potential, Eo
cell.
d. What must the partial pressures of the reactants be in order to produce the
voltage in part c?
a. The anode is where oxidation occurs, so the half reaction taking place at the anode is: O₂(g) + 4 H⁺(aq) + 4 e⁻→ 2 H₂O(l)
b. The cathode is where reduction occurs, so the half reaction taking place at the cathode is: 2 H⁺(aq) + 2 e⁻+ 2 H₂S(g) → 2 S(s) + 2 H₂O(l)
c. To calculate the standard cell potential, Eocell, we need to add the reduction potential of the cathode and the oxidation potential of the anode. The reduction potential of the cathode half reaction is +0.15 V, and the oxidation potential of the anode half reaction is -1.23 V. Therefore, Eocell = +0.15 V + (-1.23 V) = -1.08 V.
d. To produce the voltage of -1.08 V, the reaction must be spontaneous, which means that the Gibbs free energy change, ΔG, must be negative.
The relationship between ΔG, Eocell, and the equilibrium constant, K, is: ΔG = -nFEocell = -RTlnK, where n is the number of electrons transferred, F is Faraday's constant, R is the gas constant, and T is the temperature.
Solving for K, we get: K = e^(-ΔG/RT) = e^(-nFEocell/RT).
Substituting the values, we get: K = e^(-(-2)(96485 C/mol)(-1.08 V)/(8.314 J/mol-K)(298 K)) = 4.5 x 10¹⁸. Since the reaction is in acid, the partial pressure of H⁺ is 1 atm.
Using the equilibrium constant expression for the reaction, K = [S]²/[H₂S]², we can solve for the partial pressure of H₂S: P(H₂S) = [S]/√K. Substituting the values, we get: P(H₂S) = (1 atm)/√(4.5 x 10¹⁸) = 6.7 x 10⁻¹⁰atm.
Therefore, the partial pressure of H₂S must be 6.7 x 10⁻¹⁰ atm, and the partial pressure of O₂ must be 1 atm, to produce the voltage in part c.
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Symbols used in chemical equations, together with the explanations of the symbols, are shown below. Which set is correctly matched?
A. (aq), dissolved in water
B. (g), grams
C. (so), solid
D. (l), liters
The explanations aq and g are the ones that accurately explain the chemical equation. The appropriate choices are thus C. (so), solid
D. (l), liters
What are the four roles that symbols play?
Symbols serve the following four purposes: Motivating others to take action via emotion; socially uniting groups by fostering a sense of common identity and values Clarification and revelation - show insight and clarity into the divine. Communication - conveying emotional components of an event.
The product and reactant symbols have been used to represent the chemical equation. The moles of an element that underwent a reaction are contained in the chemical equation. Prior to the compound, the moles were written as the coefficient.
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Substances a-d have the following specific heats (j/g-°c):
a = 0.90, b = 1.70, c = 2.70, d = 4.18.
which substance will cool the fastest when equal masses are heated to the same temperature?
The substance that will cool the fastest when equal masses are heated to the same temperature is the one with the lowest specific heat.
This is because a substance with a lower specific heat requires less energy to raise its temperature by a certain amount, and therefore it will release heat more quickly when it cools down.
Out of the given substances, substance A has the lowest specific heat of 0.90 J/g-°C, so it will cool the fastest when equal masses are heated to the same temperature.
Substance B has a specific heat of 1.70 J/g-°C, substance C has a specific heat of 2.70 J/g-°C, and substance D has the highest specific heat of 4.18 J/g-°C.
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A chemist adds of a mercury(i) chloride solution to a reaction flask. calculate the mass in micrograms of mercury(i) chloride the chemist has added to the flask. round your answer to significant digits.
To calculate the mass of mercury(I) chloride that the chemist has added to the reaction flask, we need to know the molar mass of the compound and the number of moles of the solution added.
The molar mass of mercury(I) chloride is 232.6 g/mol. The chemist added an unspecified volume of the solution, so we cannot directly calculate the number of moles added. However, we can use the concentration of the solution, which is typically given in units of moles per liter (mol/L).
Let's assume that the concentration of the mercury(I) chloride solution is 0.1 mol/L. This means that there are 0.1 moles of mercury(I) chloride in every liter of the solution. We don't know how much of the solution the chemist added, but we can use a conversion factor to calculate the number of moles based on the volume.
For example, if the chemist added 10 mL of the solution, we can convert that to liters by dividing by 1000 (1 mL = 0.001 L).
10 mL x (0.001 L/1 mL) = 0.01 L
Now we can use the concentration to calculate the number of moles:
0.1 mol/L x 0.01 L = 0.001 mol
Finally, we can use the molar mass to convert from moles to grams:
0.001 mol x 232.6 g/mol = 0.2326 g
To convert to micrograms, we need to multiply by 1,000,000:
0.2326 g x 1,000,000 µg/g = 232,600 µg
Therefore, the mass of mercury(I) chloride added to the reaction flask is 232,600 µg, rounded to significant digits.
It's worth noting that the exact answer will depend on the actual concentration of the solution and the volume added, but this calculation provides a general approach to solving this type of problem.
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16. If the difference in electro-negativities of the combining atoms is zero, then the bond formed is a
(a) covalent bond
(b) electrovalent bond
(c) non-polar covalent bond
(d) polar covalent bond
How many lead atoms are present in a piece of lead of volume 1. 907 cm?
Useful data:
The density of Pb = 11. 34 g. Cm-3.
Avogadro's Number (NA) = 6. 022x1023 atoms. Mol-1
Give your answer to 3 significant figures
Giving your answer with specific significant figures. Use 'e' notation for powers of ten:
for example for 1. 23 x 104, enter 1. 23e4
for example for 6. 022 x 1023, enter 6. 022e23
for example for 1. 23 x 10-6, that is 0. 00000123, enter 1. 23e-6
note no gaps
The number of lead atoms in a piece of lead with a volume of 1.907 cm³ is 1.54e22 atoms.
To find this, follow these steps:
1. Calculate the mass of the lead piece using its volume and density: mass = volume x density = 1.907 cm³ x 11.34 g/cm³ = 21.61 g.
2. Determine the molar mass of lead (Pb): 207.2 g/mol.
3. Calculate the number of moles of lead in the piece: moles = mass/molar mass = 21.61 g / 207.2 g/mol = 0.104 mol.
4. Use Avogadro's number to find the number of atoms: atoms = moles x Avogadro's number = 0.104 mol x 6.022e23 atoms/mol = 1.54e22 atoms.
So, there are 1.54e22 lead atoms in the given piece of lead.
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A 25. 0 mL sample of a saturated Ca(OH)2 solution is titrated with 0. 029 M HCl, and
the equivalence point is reached after 37. 3 mL of titrant are dispensed. Based on this
data, what is the concentration (M) of Ca(OH)2?
The concentration of [tex]Ca(OH)_2[/tex] is 0.0217 M.
The balanced chemical equation for the reaction between the [tex]Ca(OH)_2[/tex] and the HCl is:
[tex]Ca(OH)_2 + 2HCl[/tex] → [tex]CaCl_2 + 2H_2O[/tex]
From this equation, we can see that 1 mole of [tex]Ca(OH)_2[/tex] reacts with 2 moles of HCl.
The number of moles of HCl used can be calculated as:
moles HCl = Molarity * Volume in liters[tex]= 0.029 M\ *\ 0.0373 L = 0.0010837\ mol[/tex]
Since the stoichiometry of the reaction is 1:2 between [tex]Ca(OH)_2[/tex] and HCl, the number of moles of [tex]Ca(OH)_2[/tex] in the 25.0 mL sample can be calculated as:[tex]moles\ Ca(OH)2 = 0.0010837\ mol / 2 = 0.00054185\ mol[/tex]
The concentration of [tex]Ca(OH)_2[/tex] can then be calculated as:
[tex]Molarity = moles[/tex] ÷ [tex]Volume\ in\ liters\ = 0.00054185\ mol[/tex] ÷ 0.025 L = 0.0217M
Therefore, the concentration of [tex]Ca(OH)_2[/tex] is 0.0217 M.
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Calculate the mass of 6. 9 moles of nitrous acid (HNO2). Explain the process or show your work by including all values used to determine the answer
The mass of 6.9 moles of nitrous acid (HNO₂) is 324.3 grams.
To calculate the mass of 6.9 moles of nitrous acid (HNO₂), follow these steps:
1. Determine the molar mass of HNO₂.
2. Multiply the molar mass by the given moles (6.9 moles) to find the mass.
Step 1: Determine the molar mass of HNO₂.
HNO₂ consists of 1 hydrogen atom, 1 nitrogen atom, and 2 oxygen atoms.
- The atomic mass of hydrogen (H) is 1 g/mol.
- The atomic mass of nitrogen (N) is 14 g/mol.
- The atomic mass of oxygen (O) is 16 g/mol.
Molar mass of HNO₂ = (1 x 1) + (1 x 14) + (2 x 16) = 1 + 14 + 32 = 47 g/mol.
Step 2: Multiply the molar mass by the given moles (6.9 moles).
Mass of HNO₂ = 6.9 moles × 47 g/mol = 324.3 g.
So, the mass of 6.9 moles of nitrous acid (HNO₂) is 324.3 grams.
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You have been supplied with a concentrated solution of calcium dihydrogen phosphate to be used in a hydroponic system to grow lettuce. The solution has a phosphorus concentration of 200 mg/ L, however, in a hydroponic nutrient solution, the common range of elemental phosphorus required is 30-50 mg/L. Explain how you would prepare a solution containing 35 mg/L phosphorus in a 500 mL volume?
To prepare a hydroponic solution with 35 mg/L of phosphorus in a 500 mL volume, you will need to dilute the concentrated calcium dihydrogen phosphate solution.
Firstly, calculate the volume of the concentrated solution required to make the desired concentration. You can apply the formula here:
C1V1 = C2V2
Where C1 is the concentration of the concentrated solution (200 mg/L), V1 is the volume of concentrated solution required, C2 is the desired concentration (35 mg/L), and V2 is the final volume of the solution (500 mL).
Substituting these values, we get:
(200 mg/L) V1 = (35 mg/L) (500 mL)
V1 = (35 mg/L) (500 mL) / (200 mg/L)
V1 = 87.5 mL
So, you need 87.5 mL of the concentrated solution to make 500 mL of the final solution with a phosphorus concentration of 35 mg/L.
To prepare the final solution, measure 87.5 mL of the concentrated solution and add it to a measuring cylinder. Add distilled water to make the remaining 500 mL, and then. Mix the solution well to ensure that the calcium dihydrogen phosphate is evenly distributed.
This will give you a hydroponic solution with a phosphorus concentration of 35 mg/L, which falls within the common range of elemental phosphorus required for growing lettuce.
What is hydroponic solution?
A Hydroponic solution, also known as hydroponic nutrient solution, is a specially formulated liquid mixture of nutrients that is used to grow plants hydroponically. Hydroponics is a method of growing plants in a soil-free medium, where the roots of the plants are suspended in a nutrient-rich solution.
How can you determine the specific heat capacity of 1. 0g of yam
Specific heat capacity is the amount of heat required to raise the temperature of a substance by one degree Celsius per unit of mass.
To determine the specific heat capacity of 1.0g of yam, we can use a simple equation:
q = m × c × ΔT
where q is the amount of heat required, m is the mass of the substance, c is the specific heat capacity, and ΔT is the change in temperature.
To measure the specific heat capacity of yam, we would first need to heat the yam to a known temperature, and then measure the amount of heat required to raise its temperature by a certain amount.
For example, we could heat 1.0g of yam to 25°C and then place it in a known amount of water at a lower temperature, such as 20°C. We could then measure the change in temperature of the water and calculate the amount of heat required to heat the yam.
By rearranging the equation above, we can solve for c:
c = q / (m × ΔT)
We can then substitute in the values we measured and calculate the specific heat capacity of the yam. This process can be repeated several times to obtain an average value for the specific heat capacity of yam.
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Put these atoms in order from most positive overall charge to least positive
overall charge.
Atom B: 24 protons, 19 electrons
+
Atom A: 14 protons, 16 electrons
Atom R: 26 protons, 24 electrons
Atom P: 8 protons, 11 electrons
← PREVIOUS
C
C
1
J
SUBMIT
C
19
The order of the atoms from most positive overall charge to least positive overall charge is: Atom B > Atom R > Atom A > Atom P.
What is the order of atoms?
To determine the order of the atoms from most positive overall charge to least positive overall charge, we need to compare the number of protons (positive charges) and electrons (negative charges) for each atom.
Atom R has 26 protons and 24 electrons. Therefore, it has a net positive charge of 2+.
Atom B has 24 protons and 19 electrons. Therefore, it has a net positive charge of 5+.
Atom A has 14 protons and 16 electrons. Therefore, it has a net negative charge of 2-.
Atom P has 8 protons and 11 electrons. Therefore, it has a net negative charge of 3-.
Therefore, the order of the atoms from most positive overall charge to least positive overall charge is:
Atom B > Atom R > Atom A > Atom P.
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Why might your value be different from absolute zero? (HINT: Think errors in the lab. )
Value might be different from absolute zero due to several factors like Measurement errors, External factors, Non-ideal conditions.
"Why might your value be different from absolute zero?" we need to understand the following terms:
1. Value: Refers to a quantity or numerical measurement in a specific context.
2. Absolute zero: The lowest possible temperature, at which all molecular motion stops. It is 0 Kelvin (K) or -273.15 degrees Celsius (°C) or -459.67 degrees Fahrenheit (°F).
Your value might be different from absolute zero due to several factors, such as:
1. Measurement errors: If you are measuring a temperature, there could be inaccuracies in your measuring device, leading to a value different from absolute zero.
2. External factors: The presence of heat or energy in your system can cause the value to deviate from absolute zero.
3. Non-ideal conditions: In real-world situations, reaching absolute zero is practically impossible due to quantum effects and other factors, causing your value to be higher than absolute zero.
By understanding these factors, you can identify why your value may differ from absolute zero.
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A car's catalytic converter combines carbon monoxide, a poisonous gas, with oxygen to form carbon dioxide gas. A balanced equation indicates the mole ratios of reactants and products. If all the reactants and products are gases, then the equation can also be read in terms of volume ratios.
1. Write the balanced equation for this reaction.
2. What volume of oxygen is required so that 630 mL of carbon monoxide gas is completely converted to carbon dioxide?
3. How many liters of carbon dioxide are produced if the catalvtic converter processes 6.25 L of carbon monoxide?
4. How much oxygen does a catalytic converter require to produce 2.50 L of carbon dioxide?
5. Assume that 425 mL of carbon monoxide and 180mL of oxygen are being processed by a catalytic
Converter. Will all of the carbon monoxide be converted to carbon dioxide? Explain your answer
1) The balanced reaction is [tex]2CO + O_{2} ---- > 2CO_{2}[/tex]
2) 313.6 mL is required so that 630 mL of carbon monoxide gas is completely converted to carbon dioxide.
3) 3.136 L are produced if the catalytic converter processes 6.25 L of carbon monoxide.
4) The volume of oxygen is 1.23L.
What is the balanced reaction?If 1 mole of CO occupies 22400 mL
x moles of CO occupies 630 mL
x = 0.028 moles
If 2 moles of CO reacts with 1 mole of oxygen
0.028 moles of CO reacts with 0.028 moles * 1/2
= 0.014 moles
Volume of oxygen required = 0.014 moles * 22400 mL
= 313.6 mL
If 1 mole of CO occupies 22.4 L
x moles of CO occupies 6.25 L
x = 0.28 moles
If 2 moles of CO produces 1 mole of carbon dioxide
0.28 moles of CO produces 0.28 * 1/2
= 0.14 moles
Volume of the carbon dioxide = 0.14 moles * 22.4 L
= 3.136 L
If 1 mole of carbon dioxide occupies 22.4 L
x moles of carbon dioxide occupies 2.5 L
x = 2.5 L * 1/22.4 L
x = 0.11 moles
If 1 mole of oxygen produces 2 moles of carbon dioxide
x moles of oxygen produces 0.11 moles of carbon dioxide
x = 0.055 moles
Volume of oxygen = 0.055 moles * 22.4 L
= 1.23L
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Meteorologists state that a "falling" barometer indicates an approaching storm. given a barometric pressure of 698.5 mm hg, express the pressure in each of the following units of pressure.
atm =
psi =
kpa =
The pressure in the each of the units of the pressure is a s:
atm = 0.91
psi = 13.5
kpa = 93.12
The barometric pressure = 698.5 mmHg
The conversion of pressure unit from mmHg to atm :
1 mmHg = 0.00131579 atm
698.5 mmHg = 0.91 atm
The 698.5 mmHg is expressed as 0.91 atm.
The conversion of pressure unit from mmHg to psi :
1 mmHg = 0.0193368 psi
698.5 mmHg = 13.5 psi
The 698.5 mmHg is expressed as 13.5 psi.
The conversion of pressure unit from mmHg to kpa :
1 mmHg = 0.133322 kpa
698.5 mmHg = 93.12 kpa
The 698.5 mmHg is expressed as 93.12 kpa.
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To convert mmHg to atm, divide the mmHg value by 760. To convert mmHg to psi, divide the mmHg value by 51.714. Therefore, 698.5 mmHg is equal to 0.924 atm, 13.37 psi and 93.5 kPa.
What is equal ?Equality is the state of having the same rights, status, and opportunities regardless of gender, race, religion, or other characteristics. It means that all people are treated without prejudice or discrimination and that everyone can access the same resources, services, and opportunities. Equality is essential to the functioning of a fair and just society, and it is one of the core values of many countries. It is also essential to achieving social and economic progress. Equality is a fundamental human right, and it is essential to creating a sense of inclusion and belonging in a society.
Atm: 0.924 atm
Psi: 13.37 psi
Kpa: 93.5 kPa
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Ketone 1 gives two different bicyclic products depending on the base used: when treated with potassium tert-butoxide at room temperature, it produces ketone 2, while when treated with LDA at low temperatures and then heated, it produces ketone 3. Write arrow-pushing mechanisms for the formation of both 2and 3and explain why the reaction conditions favor each product
Ketone 1 undergoes different reactions depending on the base used.
When treated with potassium tert-butoxide at room temperature, it produces ketone 2 via an intramolecular aldol reaction.
On the other hand, when treated with LDA at low temperatures, it undergoes a kinetic enolate formation followed by intramolecular cyclization to give an intermediate, which upon heating, eliminates lithium and produces ketone 3. The reaction conditions favor each product due to the different reactivity of the bases.
Potassium tert-butoxide is a strong base and promotes a fast aldol reaction at room temperature, while LDA is a weaker base that requires low temperatures to form the kinetically favored enolate intermediate, which upon heating, undergoes lithium elimination to give ketone 3.
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According to regulations, the legal limit for arsenic in drinking water is 0.05 ppm. If you test a sample of 100 grams of drinking water and find 0.0012 grams of arsenic, is this within the legal limit? Show your calculations.
The concentration of arsenic in the water is 12 ppm, which is higher than the legal limit of 0.05 ppm, the sample of drinking water is not within the legal limit for arsenic. Therefore, action needs to be taken to reduce the level of arsenic in the water to make it safe for drinking.
The concentration of arsenic in the water can be calculated as follows:
Concentration (ppm) = (Mass of arsenic / Mass of water) x 1,000,000
In this case, the mass of arsenic is 0.0012 grams and the mass of water is 100 grams. Substituting these values into the formula, we get:
Concentration (ppm) = (0.0012 g / 100 g) x 1,000,000
Concentration (ppm) = 12 ppm
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When a car is far away, its headlights
are bright, than when the car passes you. True/False?
Apparent brightness of a star is low bright the alar
from Farth. True/false
Answer:
Explanation:
no
What is the molar concentration of a solution formed when. 55 mol of Ca(OH)2 are dissolved in 2. 20 liters of HOH?
The molar concentration of the solution formed when 0.55 mol of Ca(OH)₂ are dissolved in 2.20 liters of HOH is 0.25 mol/L.
To find molar concentration of a solution use the formula:
Molar concentration = moles of solute / volume of solution in liters
The moles of solute are 0.55 mol of Ca(OH)₂ and the volume of the solution is 2.20 liters of H₂O.
So, the molar concentration of the Ca(OH)₂ solution is:
Molar concentration = 0.55 mol / 2.20 L
Molar concentration ≈ 0.25 mol/L
Therefore, the molar concentration of the Ca(OH)₂ solution is 0.25 mol/L.
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The separation of benzene (B) from cyclohexane (C) by distillation at 1 atm is impossible because of a minimum-boiling-point azeotrope at 54. 5 mol% benzene. However, extractive distillation with furfural is feasible. For an equimolar feed, cyclohexane and benzene products of 98 and 99 mol%, respectively, can be produced. Alternatively, the use of a three-stage pervaporation process, with selectivity for benzene using a polyethylene membrane, has received attention, as discussed by Rautenbach and Albrecht [47]. Consider the second stage of this process, where the feed is 9,905 kg/h of 57. 5 wt% B at 75C. The retentate is 16. 4 wt% benzene at 67. 5C and the permeate is 88. 2 wt% benzene at 27. 5C. The total permeate mass flux is 1. 43 kg/m2-h and selectivity for benzene is 8. Calculate flow rates of retentate and permeate in kg/h and membrane surface area in m2
The retentate flow rate is 5,021.862 kg/h and the permeate flow rate is 5,021.862 kg/h. The membrane surface area required is 3,517.948 m².
What is permeate flow ?Permeate flow is the rate at which a fluid passes through a membrane. It is a measure of the membrane's permeability, which is the ability of a substance to pass through a membrane. Permeate flow is used in many industrial processes, such as purification of fluids, separation of compounds, and concentration of liquids.
The first step is to calculate the mass flow rate of the feed. This is given by the equation:
Mass flow rate (kg/h) = Feed flow rate (kg/h) x Feed concentration (wt%)
Mass flow rate = 9,905 kg/h x 57.5 wt% = 5,686.625 kg/h
Next, we need to calculate the flow rate of the retentate and permeate in kg/h. This is given by the equation:
Flow rate (kg/h) = Mass flow rate (kg/h) x Retentate/Permeate concentration (wt%)
Retentate flow rate = 5,686.625 kg/h x 16.4 wt% = 931.939 kg/h
Permeate flow rate = 5,686.625 kg/h x 88.2 wt% = 5,021.862 kg/h
Finally, we need to calculate the membrane surface area in m². This is given by the equation:
Membrane surface area (m²) = Permeate flow rate (kg/h) / Total permeate mass flux (kg/m²-h)
Membrane surface area = 5,021.862 kg/h / 1.43 kg/m²-h = 3,517.948 m².
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Can anyone answer these questions please.
ans.1
blank 1 = 4
blank 2 = 4
blank 3 = 1
blank 4 = 8
ans.2
blank 1 = 10
blank 2 = 15
blank 3 = 1
blank 4 = 30
ans.3
blank 1 = 1
blank 2 = 2
blank 3 = 2
blank 4 = 1
blank 5 =2
Erica neutralized 80. 0 mL of 0. 70 M KOH solution with 28. 0 mL of H2SO4 solution. What was the concentration of the H2SO4 solution Erica used?
The concentration of the H₂SO₄ solution Erica used was approximately 2.0 M.
To find the concentration of H₂SO₄ solution used by Erica, we can use the concept of stoichiometry and the balanced chemical equation for the neutralization reaction between KOH and H₂SO₄:
KOH + H₂SO₄ -> K₂SO₄ + 2H2O
From the balanced equation, we can see that the mole ratio of KOH to H₂SO₄ is 1:1. This means that the number of moles of H₂SO₄ used in the reaction is equal to the number of moles of KOH. We can use this fact to calculate the number of moles of H₂SO₄ used:
moles of KOH = volume of KOH solution (in L) x concentration of KOH solution
moles of KOH = 80.0 mL x (1 L/1000 mL) x 0.70 mol/L = 0.056 mol
Since the mole ratio of KOH to H₂SO₄ is 1:1, the number of moles of H₂SO₄ used is also 0.056 mol. Now we can use the same formula as above to calculate the concentration of H₂SO₄:
concentration of H₂SO₄ = moles of H2SO4 / volume of H₂SO₄ solution (in L)
concentration of H₂SO₄ = 0.056 mol / (28.0 mL x 1 L/1000 mL) = 2.00 mol/L
Therefore, the concentration of the H₂SO₄ solution Erica used was 2.00 M.
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Explain why the following carboxylic acids cannot be prepared by a malonic ester synthesis. Part A A line-angle formula shows a ring with six vertices and alternating single and double bonds. A CH2COH group, with an O atom double-bonded to the second (from left to right) carbon atom, is attached to one of the ring vertices. A line-angle formula shows a ring with six vertices and alternating single and double bonds. A CH2COH group, with an O atom double-bonded to the second (from left to right) carbon atom, is attached to one of the ring vertices. An SN2 reaction cannot be done on benzyl bromide. An SN2 reaction cannot be done on bromobenzene. An SN2 reaction cannot be done on dibromobenzene. The bromide required for the synthesis is unstable
The first two carboxylic acids described contain a benzene ring, which is not susceptible to the malonic ester synthesis.
The malonic ester synthesis requires a compound with a methyl group adjacent to both carboxylate groups, and a benzene ring does not fulfill this requirement. The last two carboxylic acids described cannot be prepared by the malonic ester synthesis because an SN₂ reaction cannot be performed on compounds with bulky substituents or with two or more halogen atoms attached to the same carbon atom.
The synthesis requires the use of an alkyl halide that can undergo an SN₂ reaction with sodium ethoxide, but benzyl bromide, bromobenzene, and dibromobenzene are not suitable for this type of reaction. Additionally, the bromide required for the synthesis is unstable, which further complicates the reaction.
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Name the following compound: 100 POINTS
Propyl amine
Ethyl amine
Ethyl dihydrogen amine
Propyl dihydrogen amine
Answer:
C. Ethyl dihydrogen amine
Explain what sedimentation equilibrium is and how it is related to chemical equilibrium.
Answer:
Sedimentation equilibrium in a suspension of different particles, such as molecules, exists when the rate of transport of each material in any one direction due to sedimentation equals the rate of transport in the opposite direction due to diffusion.