Heating 3,3-dimethyl-2-butanol (tert-amyl alcohol) with sulfuric acid leads to the elimination of a molecule of water to form an alkene. The major organic product obtained is 2,3-dimethyl-2-butene, also known as tetramethylethylene.
The mechanism for the reaction involves protonation of the hydroxyl group by sulfuric acid, followed by loss of water to form a carbocation intermediate. The carbocation then undergoes rearrangement to form the more stable tertiary carbocation. Elimination of a proton from the tertiary carbocation leads to the formation of the alkene product.
The reaction can be summarized as follows:
[tex](CH_3)_3CCH(OH)CH_3 + H_2SO_4 \rightarrow (CH_3)_3CCH=CH_2 + H_2O + H_2SO_4[/tex]
Therefore, the correct answer is 2,3-dimethyl-2-butene.
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which of the following is not a strong acid? select the correct answer below: hydrobromic acid hydroiodic acid hydrochloric acid hydrofluoric acid
Hydrofluoric acid is not a strong acid.
Hydrofluoric acid (HF) is a weak acid because it does not completely dissociate in water to form [tex]H^+[/tex] ions. In water, HF undergoes a partial dissociation to form [tex]H^+[/tex] and [tex]F^-[/tex] ions according to the following equilibrium:
[tex]HF + H_2O[/tex] ⇌ [tex]H_3O^+ + F^-[/tex]
This equilibrium favors the reactant side, meaning that most of the HF molecules remain as HF in solution, with only a small percentage dissociating to form [tex]H^+[/tex] ions.
In contrast, hydrochloric acid (HCl), hydrobromic acid (HBr), and hydroiodic acid (HI) are strong acids because they completely dissociate in water to form [tex]H^+[/tex] ions. These strong acids have weak conjugate bases, which makes the acid dissociation reaction highly favorable.
The strength of an acid is related to its tendency to donate a proton ( [tex]H^+[/tex] ) in water. The stronger the acid, the more readily it donates [tex]H^+[/tex] ions.
Therefore, hydrochloric acid, hydrobromic acid, and hydroiodic acid are stronger acids than hydrofluoric acid.
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co2 gas is soluble in water. what would happen to the solubility of carbon dioxide gas in water as the temperature increases?
Carbon dioxide (CO2) is a gas that is slightly soluble in water. As the temperature of water increases, the solubility of CO2 decreases.
This is due to the fact that, as temperature increases, the amount of dissolved CO2 gas in water decreases.
This phenomenon is known as Henry's law, which states that the solubility of a gas in a liquid is proportional to the partial pressure of the gas above the liquid.
As temperature increases, the partial pressure of CO2 gas above the liquid increases, causing its solubility to decrease.
The solubility of CO2 gas in water is also affected by pH. In general, as the pH of water decreases, the solubility of CO2 in water increases.
This is because the solubility of CO2 in water is reduced by the presence of bicarbonate ions, which are created by the dissociation of carbonic acid, a weak acid.
As the pH decreases, the amount of bicarbonate ions in solution decreases, which in turn increases the solubility of CO2.
The solubility of CO2 gas in water decreases as temperature increases and pH decreases. As temperature increases, the partial pressure of CO2 above the liquid increases, resulting in decreased solubility.
As the pH of water decreases, the solubility of CO2 increases due to the decreased amount of bicarbonate ions in solution.
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specifically, what should you look at in the infrared spectrum of the ester you synthesized that will show the absence of the reactants?
In the infrared spectrum of the ester you synthesized, specifically, you should look for the presence of ester functional group peaks and the absence of reactants' peaks
When looking at the infrared spectrum of the ester that you synthesized, you should specifically look for the absence of the reactants. This can be seen in the form of absorption peaks in the infrared spectrum. Any absorption peaks that are present in the spectrum indicate that the reactants are still present in the ester, while a lack of absorption peaks suggests that the reactants have been fully converted into the ester. Therefore, the absence of peaks in the infrared spectrum is a good indication that the reactants have been consumed in the reaction and the synthesis was successful.
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why is it a good idea to include reactions that contain substrate but not enzyme in your kinetic analysis?
It is a good idea to include reactions that contain substrate but not enzyme in your kinetic analysis because: it provides a baseline or control for the reaction.
One of the reasons is that it provides a baseline or control for the reaction. By studying the reaction without the enzyme, one can determine how much of the reaction is due to the enzyme and how much is due to other factors.
Additionally, it can help to identify any non-specific interactions that may be occurring between the substrate and other components of the reaction. Another reason is that it can help to establish the limits of detection for the assay. This is important for ensuring that the assay is sensitive enough to detect changes in enzyme activity under various conditions.
For example, if the assay is not sensitive enough, it may not be possible to detect changes in enzyme activity due to small changes in the reaction conditions. Finally, studying reactions that contain substrate but not enzyme can help to identify any interference or background signals that may be present in the assay.
This is important for ensuring that the assay is specific to the enzyme of interest and is not measuring other unrelated activities. By including reactions that contain a substrate but not an enzyme, one can identify any background signals and subtract them from the measurement of enzyme activity to obtain a more accurate result.
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Answer with the Matching-match the letter with the correct item
Synthesis and decomposition reactions are two types of chemical reactions that involve the formation and breaking of chemical bonds between atoms and molecules.
A synthesis reaction, also known as a combination reaction, occurs when two or more reactants combine to form a single, more complex product. The general equation for a synthesis reaction is A + B → AB.
A decomposition reaction, on the other hand, is the opposite of a synthesis reaction. It occurs when a single reactant breaks down into two or more simpler products. The general equation for a decomposition reaction is AB → A + B.
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acetic acid has a ka of 1.80x10-5. what is the ph of a buffer solution made from 0.150 m hc2h3o2 and 0.530 m c2h3o2 -?
Acetic acid has a ka of 1.80x10-5. The pH of a buffer solution made from 0.150 m hc2h3o2 and 0.530 m c2h3o2 is 4.76.
The pH of a buffer solution produced from 0.150 M HC2H3O2 and 0.530 M C2H3O2 is 4.76.
The following are the steps to solve the problem:
Acetic acid is a weak acid with the formula CH3COOH, which is also known as ethanoic acid.
HC2H3O2 is the molecular formula for this substance.
Acetic acid has a Ka of 1.8 x 10-5.
The ionization of acetic acid can be expressed as follows: CH3COOH + H2O ↔ H3O+ + CH3COO-
The ionization constant, Ka, is equal to the product of the concentration of H3O+ and CH3COO- ions divided by the concentration of CH3COOH.
Hence, Ka = ([H3O+] [CH3COO-])/[CH3COOH]
The Henderson-Hasselbalch equation is used to compute the pH of a buffer solution.
pH = pKa + log (base/acid), where pKa = -logKa.
In the equation, the base is C2H3O2-, and the acid is HC2H3O2.
Substituting the values in the equation, pH = -log1.8 x 10-5 + log(0.530/0.150) = 4.76.
Therefore, the pH of a buffer solution produced from 0.150 M HC2H3O2 and 0.530 M C2H3O2 is 4.76.
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what is the [hcoo-]/[hcooh] ratio in an acetate buffer at ph 4.50? (the pka for formic acid is 3.80.) [hcoo-]/[hcooh]
The ratio of [HCO₃⁻] to [HCO₂H] in an acetate buffer is 5.01.
The ratio of [HCO₃⁻] to [HCO₂H] (formic acid) in an acetate buffer at pH 4.50 is determined by the Henderson-Hasselbalch equation:
pH = pKa + log ([HCO₃⁻]/[HCO₂H]).
[HCO₃⁻]/[HCO₂H] = 10^(pH-pKa)
= 10^(4.50 - 3.80)
= 5.01
To further understand the buffering capacity of an acetate buffer, we must first understand the role of formic acid and bicarbonate in an acetate buffer.
Formic acid is an organic acid and bicarbonate is a salt of carbonic acid. Both of these species can form and break down as needed to maintain the pH of the buffer.
As the pH of the buffer is increased, the formic acid will break down, forming more bicarbonate.
On the other hand, as the pH of the buffer is decreased, more formic acid will form, resulting in fewer bicarbonate ions.
The buffering capacity of an acetate buffer is dependent on the relative concentrations of formic acid and bicarbonate ions, and these concentrations can vary depending on the pH of the buffer.
In summary, the ratio of [HCO₃⁻] to [HCO₂H] is found to be 5.01 in an acetate buffer at pH 4.50.
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g a first-order reaction has a half-life of 23.1 s. how long does it take for the concentration of the reactant in the reaction to fall to one-sixteenth of its initial value?
Answer: It takes 92.4 s for the concentration of the reactant in the reaction to fall to one-sixteenth of its initial value.
The first-order reaction has a half-life of 23.1 s, which means that it takes 23.1 s for the concentration of the reactant to decrease to half of its initial value. Since the concentration needs to be reduced to one-sixteenth of its initial value, it will take four half-lives of the reaction, or 92.4 s in total.
This can be mathematically shown using the formula of a first-order reaction:
[A]t = [A]0 X e^(-kt)
Where:
[A]t is the concentration of the reactant at time t
[A]0 is the initial concentration of the reactant
k is the rate constant of the reaction
To calculate the time required for the concentration to fall to one-sixteenth of its initial value, the equation can be rearranged as:
t = -(1/k)ln([A]t/[A]0)
By substituting the values of the half-life, initial concentration, and the desired concentration, we can calculate the time required for the concentration of the reactant to reduce to one-sixteenth of its initial value.
Therefore, it takes 92.4 s for the concentration of the reactant in the reaction to fall to one-sixteenth of its initial value.
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oxygen gas is collected over water. the total pressure (the o2 pressure the water vapor pressure) is 748 torr. the temperature of the water is such that the water vapor pressure is 23 torr. what is the partial pressure of the oxygen gas in torr? answer:
The partial pressure of oxygen gas in torr is 725 torr. when oxygen gas is collected over water.
oxygen gas is collected over water. the total pressure (the o2 pressure the water vapor pressure) is 748 torr. the temperature of the water is such that the water vapour pressure is 23 torr. the partial pressure of the oxygen gas in torr.
The total pressure of the mixture
(the oxygen pressure + the water vapour pressure) is 748 torr.
At a temperature at which the water vapour pressure is 23 torr.
The partial pressure of the oxygen gas in torr can be calculated as follows;
partial pressure of O2 = total pressure - vapour pressure of water
= 748 torr - 23 torr= 725 torr
Therefore, the partial pressure of the oxygen gas in torr is 725 torr.
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consider the multistep reaction below. what is the balanced chemical equation of the overall reaction?
The overall reaction of the multistep reaction is: 2A + B → C + D
This reaction can be broken down into two individual steps. In the first step, A and B react to form an intermediate product, X. The balanced chemical equation for this step is: A + B → X. In the second step, the intermediate product X is reacted with A to form C and D. The balanced chemical equation for this step is:X + A → C + D
Combining these two equations yields the overall balanced chemical equation:
2A + B → C + D
In summary, the overall balanced chemical equation for the multistep reaction is 2A + B → C + D. This equation shows that two molecules of A and one molecule of B will combine to form one molecule of C and one molecule of D.
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Given that the partial charges on C and O in carbon monoxide are 0.020 and 0.020, respectively, calculate the dipole moment of CO. (The distance between the partial charges, r, is 113 pm.)
Answer:
2020 from da 230 get it right fam
Explanation:
palladium crystallizes in a face-centered cubic unit cell. its density is 12.0 g / cm3 at 27oc. calculate the atomic radius of pd.
Palladium crystallizes in a face-centered cubic unit cell. Its density is 12.0 g/cm3 at 27°C. Calculate the atomic radius of Pd.
A face-centered cubic (FCC) lattice is used by Palladium. As a result, the lattice parameter of palladium is a
=(4V/√3)^(1/3) ,
where V is the atomic volume of palladium. The formula for the density of a substance is d=m/V, where d is the density, m is the mass, and V is the volume of the substance. In this situation, m = M (mass of 1 mole of palladium), which can be expressed as M= n × m, where n is the number of moles of palladium and m is the mass of one palladium atom. Therefore, the density formula becomes
d=M/V.
Palladium's atomic volume is V=(4πr^3/3) /N_a,
where Na is Avogadro's constant (6.022 × 10^23 mol^-1). The atomic radius of Pd is given by the following formula:r=(a/2) × √2The density of Pd is given by the following formula
d=M/V
The molar mass of Pd can be calculated from its atomic weight (106.42 g/mol), M=106.42 g/mol The atomic volume of Pd is given by the following formula:
V= 4r^3/3Na
Use this value of V to determine the lattice parameter a = (4V/√3)^(1/3).r = (a/2) × √2
Calculations:d = 12.0 g/cm3M = 106.42 g/mol
V = (4πr^3/3) /N_a
Let's solve for V:
V = (4πr^3/3) /N_a = (4π (162.5 × 10^-30 m)^3/3) / (6.022 × 10^23 mol^-1) = 8.927 × 10^-6 cm^3/mol
The lattice parameter can be determined now
:a = (4V/√3)^(1/3) = (4 (8.927 × 10^-6 cm^3/mol) / √3)^(1/3) = 3.891 × 10^-8 cmThe atomic radius can be determined:r = (a/2) × √2 = (3.891 × 10^-8 cm/2) × √2 = 1.096 × 10^-8 cm
The atomic radius of Pd is 1.096 × 10^-8 cm.
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explain why oxygen forms 2 bonds to hydrogen to make a water molecule, while nitrogen forms 3 bonds to make a molecule of ammonia
Oxygen and nitrogen are both nonmetals, meaning they form covalent bonds when they react.
Oxygen forms two covalent bonds with hydrogen because it has six valence electrons and needs two more electrons to complete its octet. Nitrogen has five valence electrons and needs three more electrons to complete its octet, so it forms three covalent bonds with hydrogen. The chemical formula for a water molecule is H2O, meaning that two hydrogen atoms are bonded to one oxygen atom. The chemical formula for ammonia is NH3, meaning that three hydrogen atoms are bonded to one nitrogen atom. The bond between hydrogen and oxygen is a polar covalent bond, while the bond between hydrogen and nitrogen is a non-polar covalent bond. This is due to the difference in electronegativity between oxygen and nitrogen, which causes oxygen to be more electronegative than nitrogen.
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quartz is a solid in which atoms are not arranged in an orderly pattern. group of answer choices true false
Quartz is a solid in which atoms are not arranged in an orderly pattern.
The given statement is false.
Quartz is a type of mineral that is naturally occurring. It has a chemical formula of SiO2 or silicon dioxide, and its crystal structure is hexagonal or trigonal in shape. Quartz is one of the most abundant minerals on the earth's surface. It is composed of tiny particles of silicon dioxide, which have a distinctive tetrahedral arrangement.
The atoms in quartz are arranged in an orderly pattern, which makes it a crystalline solid. These orderly arrangements of atoms are what give quartz its unique physical and chemical properties.Quartz is a hard, durable mineral that is used in many different industries. It is used to make glass, ceramics, electronics, and semiconductors, among other things.
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a polar covalent bond is associated with which of the following? group of answer choices interactions between nuclei unequal sharing of electrons equal sharing of electrons the transfer of electrons
A polar covalent bond is associated with unequal sharing of electrons.
A polar covalent bond is a covalent bond in which electrons are not equally shared between the bonded atoms. It is formed when two or more atoms share electrons in such a manner that the nucleus of one atom exerts a greater attraction on the electrons than the other atom.
As a result of the unequal sharing of electrons, the atoms have partial charges. In polar covalent bonds, the electrons spend more time near the atom with a stronger nucleus. As a result, one atom in a polar covalent bond becomes partially negative, and the other becomes partially positive. Polar covalent bonds can be found in a variety of compounds, including water, ammonia, and hydrogen chloride, among others.
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a sample is sent to the laboratory for an anti-xa assay. the result of the ptt is 65.7 seconds. the result of the anti-xa assay is 0.9 u/ml of heparin. the patient is on lovenox. their anti-xa level is:
b. Therapeutic. For treatment dosage therapy, the therapeutic anti-Xa level is between 0.5 and 1 units/mL. For prophylactic dosage treatment, the ideal anti-Xa level is between 0.2 and 0.4 units/ml.
The activity of heparin, including low molecular weight heparin, is measured using the anti-Xa assay. Anti Xa is an ambiguous name. Heparin activity is what the lab truly reports when it says "against Xa." Therefore, low anti-Xa correlates with lower heparin activity, whereas high Xa correlates with higher heparin activity. The medicine and the indication both affect the therapeutic anti-Xa activity. Unfractionated heparin has a different range than low molecular weight heparin. For the treatment of venous thromboembolism, a therapeutic range for unfractionated heparin is 0.35–0.7 and for low molecular weight heparin, it is 0.5–1. 10% less is the suggested goal for acute coronary syndrome.
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Complete Question:
A sample is sent to the laboratory for an anti-Xa assay. The result of the PTT is 65.7 seconds. The result of the anti-Xa assay is 0.9 U/mL of heparin. The patient is on Lovebox. Their anti-Xa level is:
a. subtherapeutic
b. therapeutic
c. supratherapeutic
d. prophylactic
generally only the carbonates of the group 1 elements and the ammonium ion are soluble in water; most other carbonates are insoluble. how many milli- liters of 0.125 m sodium carbonate solution would be needed to precipitate the calcium ion from 37.2 ml of 0.105 m cacl2 solution?
The volume of the sodium carbonate needed to precipitate is 31.248 ml. This is calculated using the dilution formula.
The molarity of the solution and the volume of the first solution can be correlated with the molarity and the volume of diluted solution. It is called as dilution formula.
Molar concentration is the another term for molarity. Molarity is a measure of the concentration of a chemical species in particular of a solute in a solution in terms of amount of substance per unit volume of solution.
The expression for molarity of the solution is,
M1 V1 = M2 V2
here we have 0.125 m sodium carbonate solution would be needed to precipitate the calcium ion from 37.2 ml of 0.105 m cacl2 solution.
putting all the values we get,
0.105 * 37.2 = 0.125 * V2
V2 = 31.248
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What is the binding energy b of the last neutron of silicon‑30? the atomic mass of silicon‑30 is 29. 973770 u, whereas the atomic mass of silicon‑29 is 28. 976495 u
The binding energy of the last neutron in silicon-30 is 2.346 × 10^-12 J.
The binding energy of a nucleus is the energy required to separate all of its constituent nucleons (protons and neutrons) from each other to an infinite distance. The binding energy per nucleon is a measure of the stability of a nucleus, with higher values indicating greater stability.
To calculate the binding energy of the last neutron in silicon-30, we need to use the atomic masses of silicon-30 and silicon-29 to determine the mass defect of silicon-30:
mass defect = (atomic mass of protons and neutrons) - (atomic mass of nucleus)
The atomic mass of silicon-30 is 29.973770 u, and the atomic mass of silicon-29 is 28.976495 u. Therefore, the mass defect of silicon-30 is:
mass defect = (30 protons + 30 neutrons) × 1.008665 u - 29.973770 u
mass defect = 0.259625 u
This means that the total binding energy of the silicon-30 nucleus is:
binding energy = mass defect × c^2
where c is the speed of light in a vacuum, which is approximately 2.998 × 10^8 m/s.
binding energy = 0.259625 u × (1.66054 × 10^-27 kg/u) × (2.998 × 10^8 m/s)^2
binding energy = 2.335 × 10^-11 J
Since we are interested in the binding energy of the last neutron in silicon-30, we need to subtract the binding energy of the silicon-29 nucleus (which has 29 neutrons) from the binding energy of the silicon-30 nucleus:
binding energy of last neutron = binding energy of silicon-30 nucleus - binding energy of silicon-29 nucleus
binding energy of last neutron = (30 nucleons × 2.335 × 10^-11 J) - (29 nucleons × 2.308 × 10^-11 J)
binding energy of last neutron = 2.346 × 10^-12 J.
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what does the retention factor mean in terms of solubility of the pigments in the mobile phase and their interactions with the stationary phase
In terms of the solubility of the pigments in the mobile phase and their interactions with the stationary phase, the retention factor is an indicator. It is a measure of how well the pigments bind to the stationary phase relative to the mobile phase.
The retention factor in chromatography refers to the distance traveled by the compound from the starting line to the solvent front divided by the distance traveled by the solvent front.
It is the ratio of the distance that the compound traveled (in a particular solvent system) to the distance traveled by the solvent. The stationary phase can either be polar or non-polar.
The higher the retention factor, the better the pigments bind to the stationary phase and the less soluble they are in the mobile phase.
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how successful was the buffer solution in resisting ph changes when an additional amont of strong acid or a strong base was added
The effectiveness of a buffer solution in resisting pH changes is determined by the concentration ratio of the conjugate base and acid, as well as the buffer capacity.
A buffer is defined as a chemical substance or mixture of substances that have the ability to minimize a change in pH when an additional amount of strong acid or a strong base is added. How successful was the buffer solution in resisting pH changes when an additional amount of strong acid or a strong base was added? The effectiveness of a buffer solution in resisting pH changes is determined by the buffer capacity. A buffer has a strong ability to resist changes in pH when there is a high buffer capacity. A buffer solution is created by mixing a weak acid and its corresponding salt, or a weak base and its corresponding salt, in equal amounts. The buffer solution can effectively resist pH changes when a small amount of strong acid or strong base is added to it. When a strong acid is added to a buffer solution, the acid is neutralized by the buffer's weak base component. When a buffer solution is subjected to a strong base, it reacts with the buffer's weak acid component to produce water and the conjugate base of the buffer. The buffer capacity is a measure of the amount of acid or base that can be added to the buffer without causing a significant change in pH.
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The smallest unit of life that can sustain itself is called an organism or an biosphere or a population
The smallest unit of life that can sustain itself is called an organism.
An organism is a living entity that is composed of one or more cells, which are the basic structural and functional units of life. These cells are capable of carrying out all the necessary processes for the organism's survival, including metabolism, growth, reproduction, and response to stimuli. An organism can exist as a single-celled or multi-celled entity, and can range in size from microorganisms like bacteria to large mammals like elephants. The biosphere is the term used to describe the global ecological system that encompasses all living organisms and their interactions with each other and their physical environment. A population is a group of individuals of the same species living in a specific geographic area.
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the ph of a liquid is a measure of its acidity or alkalinity. the normal range of ph of blood is:
Answer: The pH of a liquid is a measure of its acidity or alkalinity. The normal range of pH of blood is 7.35-7.45.
What is pH?
A pH of 7 is neutral, a pH of less than 7 is acidic, and a pH of greater than 7 is alkaline. The pH of a solution is calculated as the negative logarithm of the hydrogen ion concentration (pH = -log[H+]), which varies from 0 to 14.The normal range of pH of blood is 7.35-7.45, which is slightly alkaline.
Maintaining the appropriate pH level in the bloodstream is critical for the body to function properly. Blood pH can be affected by a variety of factors, including respiratory and metabolic disorders. When the pH of the blood falls below 7.35, a condition known as acidosis develops. When the pH of the blood rises above 7.45, a condition known as alkalosis develops. Both acidosis and alkalosis can have serious health consequences.
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how much oxygen is needed to completely oxidize 1.67*10-3 m glucose solution (c6h12o6) completely to co2 and h2o?
8 moles of oxygen are required to completely oxidize 1.67*10-3 m glucose solution (C6H12O6) completely to CO2 and H2O.
In order to completely oxidize 1.67*10-3 m glucose solution (C6H12O6) completely to CO2 and H2O, 8 moles of oxygen are required.
The balanced equation of the reaction, which is: C6H12O6 + 6O2 ---> 6CO2 + 6H2O.
As there are 6 moles of oxygen molecules on the reactant side, 8 moles of oxygen molecules are needed to completely oxidize 1.67*10-3 m of glucose solution.
This can also be calculated by the equation n=N/V, where n is the molarity of the solution, N is the number of moles of solute and V is the volume of the solution.
Therefore, 8 moles of oxygen is equal to the molarity of the glucose solution multiplied by the volume.
The reaction between oxygen and glucose to form CO2 and H2O is an oxidation reaction. In oxidation reactions, the reactant molecules are oxidized, and as a result, oxygen is reduced.
Therefore, oxygen is needed for the oxidation of glucose molecules to occur. In other words, without the presence of oxygen, the oxidation of glucose to CO2 and H2O cannot occur.
In conclusion, 8 moles of oxygen are required to completely oxidize 1.67*10-3 m glucose solution (C6H12O6) completely to CO2 and H2O.
This can be calculated by the balanced equation of the reaction or by the equation n=N/V. This is an oxidation reaction, meaning oxygen is necessary for the oxidation of glucose molecules to occur.
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The equilibrium constant, Kc, for the following reaction is 11.8 at 752 K. 2NH3(g) N2(g) + 3H2(g) Calculate Kc at this temperature for the following reaction: 1/2N2(g) + 3/2H2(g) NH3(g) The equilibrium constant, Kc, for the following reaction is 5.70 at 719 K. 2NH3(g) N2(g) + 3H2(g) Calculate Kc at this temperature for the following reaction: NH3(g) 1/2N2(g) + 3/2H2(g)
The equilibrium constant for the new reaction at 752 K is approximately 0.29 and at 719 K is approximately 0.42.
Step wise explanation:
1) For the first reaction, the equilibrium constant (Kc) is given as 11.8 at 752 K for the reaction:
[tex]2NH_{3}[/tex](g) ⇌ [tex]N_{2}[/tex](g) + [tex]3H_{2}[/tex](g)
You are asked to calculate Kc for the following reaction:
[tex]1/2N_{2} + 3/2H_{2}[/tex] ⇌ [tex]NH_{3}[/tex](g)
To find Kc for the new reaction, note that it is the reverse of the original reaction with all coefficients divided by 2. To calculate the equilibrium constant for the reverse reaction, take the reciprocal of the original Kc, and then raise it to the power of the coefficients ratio (1/2):
Kc (new) =[tex]\sqrt{ (1 / Kc (original))}[/tex] = [tex]\sqrt{(1 / 11.8)}[/tex] ≈ 0.29
So, the equilibrium constant for the new reaction at 752 K is approximately 0.29.
2) For the second reaction, the equilibrium constant (Kc) is given as 5.70 at 719 K for the reaction:
[tex]2NH_{3}[/tex](g) ⇌ [tex]N_{2}[/tex](g) + [tex]3H_{2}[/tex](g)
You are asked to calculate Kc for the following reaction:
[tex]NH_{3}[/tex](g) ⇌ [tex]1/2N_{2}[/tex](g) + [tex]3/2H_{2}[/tex](g)
This new reaction is the reverse of the original reaction with all coefficients divided by 2. Similar to the first case, take the reciprocal of the original Kc and then raise it to the power of the coefficients ratio (1/2):
Kc (new) = [tex]\sqrt{(1 / Kc (original))}[/tex] = [tex]\sqrt{(1 / 5.70)}[/tex] ≈ 0.42
So, the equilibrium constant for the new reaction at 719 K is approximately 0.42.
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100cm3 of a gas at 27degree Celsius exert a pressure of its volume is increased to 200cm3 at 127 degrees Celsius
Answer: 100cm3 of gas at 27°c exert a pressure of 750mmHg. Calculate its pressure if it's volume is increased to 250cm3 at 127°c? In Chemistry
Explanation:
polypropylene is made by polymerizing propene, c3h6. how many molecules of propene must be polymerized to make 3.50 g of polypropylene?
The number of molecules of propene that must be polymerized to make 3.50 g of polypropylene is 5.02 x 10²² molecules.
In order to answer this question, we must first understand the concept of a mole. A mole is a unit of measurement that is equal to 6.022 x 10^23 molecules or particles. This means that in order to calculate the number of molecules of propene required to make 3.50 g of polypropylene, we must convert the mass given (3.50 g) into moles.
We know that the molecular weight of propene is 42g/mol, so we can use the following equation to find the number of moles of propene required: 3.50 g / 42g/mol = 0.0834 mol.
Since a mole is equal to 6.022 x 10²³ molecules of propene, we can now use this equation to find the number of molecules required:
0.0834 mol x (6.022 x 10²³ molecules/mol) = 5.02 x 10²² molecules of propene.
Therefore, in order to make 3.50 g of polypropylene, 5.02 x 10²² molecules of propene must be polymerized.
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a scientist conducts an experiment to determine the rate of the following reaction: if the initial concentration of n2 was 0.400 m and the concentration of n2 was 0.350 m after 0.100 s, what is the average rate of reaction over the first 100 milliseconds?
After 0.100 s, the average rate of reaction over the first 100 milliseconds is 0.25 mol s^-1. if the initial concentration of n2 was 0.400 m and the concentration of n2 was 0.350 m.
The average rate of reaction over the first 100 milliseconds when the initial concentration of N2 was 0.400 M and the concentration of N2 was 0.350 M after 0.100 s can be calculated as follows:
Average rate of reaction = {N2 consumed or produced in mol} / {time in seconds}
The balanced chemical equation for the reaction is:
N2(g) + 3H2(g) → 2NH3(g)
As per the given equation, one mole of N2 reacts to produce two moles of NH3. So, the mole of N2 consumed in the reaction would be equal to half the mole of NH3 produced.
Therefore, mole of N2 consumed = (1/2) × (0.050 M) = 0.025 M
Now, the average rate of reaction can be calculated as follows:
Average rate of reaction = {N2 consumed or produced in mol} / {time in seconds}
= 0.025 mol / 0.100 s
= 0.25 mol s^-1
Therefore, the average rate of reaction over the first 100 milliseconds is 0.25 mol s^-1.
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Match the atomic particles with their characteristics.
1. atomic mass = 4
2. mass of electron; positive charge
3. 100 percent energy; zero mass
4. mass <1; unstable charge (+)
5. electron emitted from the nucleus
alpha
gamma
meson
beta
positron
Answer:
alpha: atomic mass = 4
beta: mass of electron; positive charge
gamma: 100 percent energy; zero mass
positron: mass <1; unstable charge (+)
beta: electron emitted from the nucleus
Note: Mesons are particles composed of a quark and an antiquark and do not fit the descriptions provided.
an aqueous potassium carbonate solution is made by dissolving 5.84 5.84 moles of k2co3 k 2 co 3 in sufficient water so that the final volume of the solution is 2.20 l 2.20 l . calculate the molarity of the k2co3 k 2 co 3 solution.
The molarity of the K₂CO₃ solution is 2.65 m.
The molarity of an aqueous potassium carbonate solution can be calculated by using the following formula:
Molarity = moles of solute / liters of solution.
In this case, the moles of solute is 5.84 and the volume of the solution is 2.20 liters. Therefore, the molarity of the potassium carbonate solution is 5.84 moles / 2.20 liters = 2.65 m.
Molarity is an important concept in chemistry and is used to measure the concentration of a solution. Molarity is expressed in terms of moles of solute per liter of solution. In this case, the solution contains 5.84 moles of potassium carbonate per 2.20 liters of water. This makes the molarity of the solution 2.65 m.
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how could you perform an experiment by adjusting the ionic concentrations to determine the cause of the resting potential?
To perform an experiment to determine the cause of the resting potential by adjusting the ionic concentrations, you will need to complete the following steps.
First, you should set up the appropriate apparatus for the experiment. This will include a solution chamber, an electrode, a reference electrode, and a recording device.
Second, you should prepare the solutions in the chamber, adjusting the concentrations of the various ions. You may want to begin with a balanced solution, then adjust one of the ions while keeping the others constant.
Third, you should measure the resting potential of the cell. Record the values of the resting potential as you adjust the ion concentrations.
Fourth, you should analyze the data. You can look for correlations between the resting potential and the concentration of the ions.
Finally, you should form a conclusion. From your data, you should be able to determine which ion(s) are responsible for the resting potential.
By following these steps, you can conduct an experiment to determine the cause of the resting potential by adjusting the ionic concentrations.
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